26650-75-9Relevant academic research and scientific papers
Oxygen catalyzed mobilization of iron from ferritin by iron(iii) chelate ligands
Bou-Abdallah, Fadi,McNally, Justin,Liu, Xing Xin,Melman, Artem
, p. 731 - 733 (2011)
Tridentate chelate ligands of 2,6-bis[hydroxy(methyl)amino]-1,3,5-triazine family rapidly release iron from human recombinant ferritin in the presence of oxygen. The reaction is inhibited by superoxide dismutase, catalase, mannitol and urea. Suggested rea
IMPROVEMENT OF THE SELECTIVITY OF ALKOXYLATION OF CYANURIC CHLORIDE.
Koryakov,Koshokov,Nikitin,Marchukov,V'yunov
, p. 1309 - 1310 (2007/10/02)
Study of the quantitative relationships of the alkoxylation reaction and optimization of the complex reaction based on a mathematical model show that individual monoalkoxy-s-triazines free from 5-15% of dialkoxy-s-triazines cannot be obtained in aqueous acetone solutions. It is found that if the reaction is conducted in the basic bipolar aprotic solvent dimethylacetamide it proceeds selectively with exclusive formation of monoalkoxy-s-triazines. It can be seen from the data that the nature of the solvent does not affect selectivity of the reaction significantly. It is shown that when cyanuric chloride reacts with amides left bracket dimethylformamide (DMFA), N-methylformamide right bracket hygroscopic hydrolytically unstable products of the salt type are formed. The intermediates react with nucleophiles, such as aniline, to form substituted triazines. The reaction proceeds analogously with alcohols, and the hydrogen chloride evolved is bound irreversibly by dimethylacetamide.
