2677-32-9

Basic information

• Product Name: Phenol, 2,6-bis[(2-hydroxyphenyl)methyl]-
• CAS NO: 2677-32-9
• Molecular Formula: C20H18O3
• Molecular Weight: 306.361
• Mol File: 2677-32-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phenol, 2,6-bis[(2-hydroxyphenyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2,6-bis[(2-hydroxyphenyl)methyl]-(2677-32-9)
• EPA Substance Registry System: Phenol, 2,6-bis[(2-hydroxyphenyl)methyl]-(2677-32-9)

Safety Data

• Hazardous Substances Data: 2677-32-9(Hazardous Substances Data)

Upstream product

• 2467-02-9 Bis(2-hydroxyphenyl)methane 
• 90-01-7 salicylic alcohol 
• 6642-07-5 4-chloro-2,6-bis(5-chloro-2-hydroxybenzyl)phenol 
• 2937-59-9 2,6-bis(hydroxymethyl)phenol 
• 108-95-2 phenol 
• 35280-40-1 4-bromo-2,6-bis(5'-bromo-2'-hydroxy-α-tolyl)phenol 
• 2372-45-4 sodium butanolate 
• 106-41-2 4-bromo-phenol 
• 17026-49-2 4-chloro-2,6-bis(hydroxymethyl)phenol 
• 106-48-9 4-chloro-phenol 

Downstream Products

• 14079-42-6 2,6-di(o-anisyl)anisole 
• 824424-48-8 tris-(ethylphenoxy acetate) 
• 824424-49-9 triphenoxyacetic acid 
• 248590-47-8 25,26,27,28-tetrakis(hydroxy)calix[4]arene 
• 103511-76-8 2,6-Bis-(2-hydroxy-5-phenylazo-benzyl)-4-phenylazo-phenol 
• 103510-53-8 C₃₈H₂₄N₆O₁₅ 
• 34072-08-7 4-bromo-2,6-bis-(3,5-dibromo-2-hydroxy-benzyl)-phenol 

Relevant articles and documents

Solvent-free synthesis of trisphenols as starting precursors for the synthesis of calix[4]arenes using sulfonated multi-walled carbon nanotubes

The condensation of phenol derivatives (12 substrates) with 2,6-bis(hydroxymethyl)phenols (BMP) (6 examples) is reported using sulfonated multi-walled carbon nanotubes (SO3H@MWCNTs) under solvent-free conditions as starting precursors for the synthesis of macrocyclic molecules of calix[4]arenes. The new protocol provides a series of trisphenol derivatives (21 examples) in high yields (up to 94%) and relatively short reaction times (15-120 min). Also, direct synthesis of calix[4]arenes from different trisphenols by use of the catalyst was reported (5 examples). Furthermore, the synthesized calix[4]arene was obtained using a one-pot method from simple and easily available starting materials such as p-cresol for the synthesis of 5,11,17,23-tetramethylcalix[4]arene-25,26,27,28-tetraol. Also, in this process SO3H@MWCNTs can be reused for seven runs with almost consistent efficiency and can be recovered by easy filtration.