2696-22-2

Basic information

• Product Name: Cyclohexanol, 1-(3-buten-1-ynyl)-
• CAS NO: 2696-22-2
• Molecular Formula: C10H14O
• Molecular Weight: 150.221
• Mol File: 2696-22-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 1-(3-buten-1-ynyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 1-(3-buten-1-ynyl)-(2696-22-2)
• EPA Substance Registry System: Cyclohexanol, 1-(3-buten-1-ynyl)-(2696-22-2)

Safety Data

• Hazardous Substances Data: 2696-22-2(Hazardous Substances Data)

Upstream product

• 689-97-4 3-buten-1-yne 
• 108-94-1 cyclohexanone 
• 14763-72-5 3-buten-1-ynylmagnesium bromide 
• 2768-02-7 (vinyl)trimethoxylsilane 
• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 593-60-2 Vinyl bromide 

Downstream Products

• 23186-27-8 1-cyclohexylidene-4-methoxy-butan-2-one 
• 101431-01-0 4-(1-but-3-en-1-ynyl-cyclohexyl)-phenol 
• 4852-00-0 1-(but-3-en-1-yn-1-yl)cyclohex-1-ene 
• 88920-69-8 cyclohexyl-1 pentadiene-2,4 ol-1 
• 92802-93-2 (C₂H₅)3SnC(cyclo-C₆H₁₀OH)CCHCH₃ 
• 92803-03-7 (C₂H₅)3SnCH₂CH₂CC(cyclo-C₆H₁₀OH) 
• 876306-45-5 1-Cyclohexyliden-4-(4-hydroxy-3-methyl-phenyl)-buten-⁽²⁾ 
• 93998-13-1 1-Cyclohexyliden-4-(3,4-dimethoxy-phenyl)-buten-⁽²⁾ 
• 94264-87-6 1-(Buten-3-in-1-yl)-1-(3,4-dimethoxy-phenyl)-cyclohexan 
• 93542-18-8 1-Butyl-1-(4-hydroxy-3-methoxy-phenyl)-cyclohexan 
• 93542-19-9 1-Cyclohexyl-4-(4-hydroxy-3-methoxy-phenyl)-butan 
• 5445-30-7 1-butyl-cyclohexanol 
• 107153-19-5 1-(1-acetoxy-cyclohexyl)-but-3-en-1-one 
• 105520-28-3 1-(1-acetoxy-cyclohexyl)-butan-1-one 

Relevant articles and documents

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Direct N- and C-vinylation with trimethoxyvinylsilane

Treatment of nucleobases, nucleosides, 5-membered N-heterocycles and terminal alkynes with trimethoxyvinylsilane in the presence of copper(II) acetate-TBAF system as catalyst affords the vinylation products.

SYNTHESIS OF TERTIARY ACETYLENIC ALCOHOLS AND THEIR ETHERS IN THE KOH-DMSO SYSTEM.

The authors developed a universal single-stage method of synthesis of acetylenic alcohol ethers, including allyl and propargyl. Conducting the synthesis in one preparative stage is due to the fact that etherification of acetylenic alcohol alcoholates by organyl halides takes place in the same apparatus without separation of the intermediate product, i. e. , the synthesis is actually reduced to successive treatment of ketone with acetylene (or vinylacetylene) and organyl halides. The yield of ethers is weakly dependent on the structure of the ketone and organyl halide radicals. In the case of propargyl chloride, the formation of dipropargyl ether is observed (yield of 5%), which indicates the possibility of partial hydrolysis of the halide.