27039-14-1

Basic information

• Product Name: pyridin-3-yl benzoate
• Synonyms: pyridin-3-yl benzoate
• CAS NO: 27039-14-1
• Molecular Formula: C₁₂H₉NO₂
• Molecular Weight: 199.20536
• Mol File: 27039-14-1.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: pyridin-3-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: pyridin-3-yl benzoate(27039-14-1)
• EPA Substance Registry System: pyridin-3-yl benzoate(27039-14-1)

Safety Data

• Hazardous Substances Data: 27039-14-1(Hazardous Substances Data)

Upstream product

• 109-00-2 3-HYDROXYPYRIDINE 
• 98-88-4 benzoyl chloride 
• 110-86-1 pyridine 
• 1242438-11-4 O-phenyl O-3-pyridinyl thiocarbonate 
• 37525-46-5 2-(3-pyridinyloxy)benzothiazole 
• 93-99-2 benzoic acid phenyl ester 
• 10349-38-9 p-methoxyphenylisonitrile 
• 1426821-25-1 N-(2-oxoethyl)-N-(1-phenylvinyl)benzamide 

Downstream Products

• 99970-12-4 benzoic acid-(1-oxy-[3]pyridyl ester) 
• 28232-53-3 3-(4-nitro-phenoxy)-pyridine 
• 2005-08-5 4-chlorophenyl benzoate 
• 37525-46-5 2-(3-pyridinyloxy)benzothiazole 
• 93-99-2 benzoic acid phenyl ester 
• 66068-53-9 2-(3-pyridinyloxy)-4,6-diphenyl-1,3,5-triazine 
• 2402-77-9 2,3-dichloro-pyridine 
• 6636-78-8 2-chloro-3-hydroxypyridine 

Relevant articles and documents

Thieme Chemistry Journals Awardees - Where Are They Now? Rhodium-Catalyzed Synthesis of Unsymmetric Di(heteroaryl) Ethers Using Heteroaryl Exchange Reaction

Unsymmetric di(heteroaryl) ethers were synthesized by the rhodium-catalyzed heteroaryl exchange reaction of heteroaryl aryl ethers and heteroaryl esters at equilibrium. Diverse unsymmetric di(heteroaryl) ethers containing five- and six-membered heteroaren

Nickel-Catalyzed Decarbonylative Coupling of Aryl Esters and Arylboronic Acids

A variety of functionalized biaryls can be accessed by coupling aryl and heteroaryl esters with boronic acids in Suzuki-Miyaura-type decarbonylative cross-coupling catalyzed by an affordable catalyst system composed of Ni(cod)2 and PCy3. The methodology is tolerant of a variety of functional groups and presents an attractive alternative to the use of palladium catalysis currently used in industry to acquire such bis(hetero)aryls, but also reveals challenges associated with nickel catalysis of esters in cross-coupling chemistry.

Radical OfC transposition: A metal-free process for conversion of phenols into benzoates and benzamides

We report a metal-free procedure for transformation of phenols into esters and amides of benzoic acids via a new radical cascade. Diaryl thiocarbonates and thiocarbamates, available in a single high-yielding step from phenols, selectively add silyl radicals at the sulfur atom of the CdS moiety. This addition step, analogous to the first step of the Barton-McCombie reaction, produces a carbon radical which undergoes 1,2 OfC transposition through an O-neophyl rearrangement. The usually unfavorable equilibrium in the reversible rearrangement step is shifted forward via a highly exothermic C-S bond scission in the O-centered radical, which furnishes the final benzoic ester or benzamide product. The metal-free preparation of benzoic acid derivatives from phenols provides a potentially useful alternative to metal-catalyzed carbonylation of aryl triflates.