pyridin-3-yl benzoate

Base Information

• Chemical Name: pyridin-3-yl benzoate
• CAS No.: 27039-14-1
• Molecular Formula: C12H9NO2
• Molecular Weight: 199.209
• Mol file: 27039-14-1.mol

Synonyms:3-Pyridyl benzoate;Benzoesaeure-[3]pyridylester;3-benzoylpyridine;3-pyridylbenzoate;benzoic acid-[3]pyridyl ester;3-benzoyloxy-pyridine;

Chemical Property of pyridin-3-yl benzoate

Chemical Property:

• PSA: 39.19000
• LogP: 2.30080

Purity/Quality:

Pyridin-3-ylbenzoate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of pyridin-3-yl benzoate

There total 5 articles about pyridin-3-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

3-HYDROXYPYRIDINE (109-00-2) + p-methoxyphenylisonitrile (10349-38-9) + N-(2-oxoethyl)-N-(1-phenylvinyl)benzamide (1426821-25-1) → benzoic acid 3-pyridyl ester (27039-14-1) + 4-(4-methoxyphenylamino)-6-phenylpyridin-3-yl benzoate (1426821-55-7)

Guidance literature:

With zinc trifluoromethanesulfonate; In acetonitrile; at 20 ℃; Molecular sieve;

DOI:10.1021/ja401701x

Reference yield: 40.0%

3-HYDROXYPYRIDINE (109-00-2) + benzoyl chloride (98-88-4) → benzoic acid 3-pyridyl ester (27039-14-1)

Guidance literature:

With dmap; triethylamine; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1002/ejoc.201500630

Reference yield: 39.0%

2-(3-pyridinyloxy)benzothiazole (37525-46-5) + benzoic acid phenyl ester (93-99-2) → benzoic acid 3-pyridyl ester (27039-14-1) + phenyl 2-benzothiazolyl ether (23019-08-1)

Guidance literature:

With hydridotetakis(triphenylphosphine)rhodium(I); In chlorobenzene; for 5h; Reflux;

DOI:10.1055/s-0036-1588801

upstream raw materials:

3-HYDROXYPYRIDINE

benzoyl chloride

pyridine

O-phenyl O-3-pyridinyl thiocarbonate

Downstream raw materials:

benzoic acid-(1-oxy-[3]pyridyl ester)

1-phenyl-propan-1-one

Heptanophenone

3-HYDROXYPYRIDINE