27164-48-3

Upstream product

• 95-47-6 o-xylene 
• 538-51-2 benzylidene phenylamine 
• 42092-05-7 tetraethyl [1,2-phenylene-bis-(methylene)]bis(phosphonate) 
• 100-52-7 benzaldehyde 
• 100-42-5 styrene 
• 583-53-9 2,3-dibromobenzene 
• 95-50-1 1,2-dichloro-benzene 
• 19493-09-5 Methylenetriphenylphosphorane 

Downstream Products

• 85157-53-5 meso-1,2-Bis(2,2-dichlor-t-3-phenyl-r-1-cyclopropyl)benzol 
• 85157-52-4 meso-1,2-Bis(2,2-dibrom-t-3-phenyl-r-1-cyclopropyl)benzol 
• 18888-80-7 1,2-Bis(β-phenylethyl)benzene 
• 140650-95-9 2-(β-Phenylethyl)stilbene 
• 140650-94-8 1-Benzyl-2-phenyl-3H-indene 
• 13203-60-6 1,2-bis(2-phenylethynyl)benzene 
• 18888-81-8 o-<β-Phenyl-ethyl>-stilben 
• 14272-68-5 (Z)-2-phenyl-1-(phenylmethylene)-1H-indene 
• 18888-72-7 (2)-1-(α-Brom-benzyliden)-2-phenyl-inden 
• 14272-89-0 3-Benzoyl-1,1-dibrom-2-phenyl-inden 
• 18907-07-8 (E)-3-iodo-1-[iodo(phenyl)methylene]-2-phenyl-1H-indene 
• 18907-08-9 (Z)-3-iodo-1-[iodo(phenyl)methylene]-2-phenyl-1H-indene 
• 27286-71-1 1-Phenyl-ethinyl-2-<β-phenyl-ethyl>-benzol 
• 27286-89-1 1-(1-Bromo-2-phenyl-ethyl)-2-phenethyl-benzene 

Relevant academic research and scientific papers

Amino oxazolines as easily accessible water stable ligands for palladium catalysed aqueous Heck reaction

A series of amino oxazolinyl ligands were screened for palladium catalysed Heck reaction. These ligands work well as phosphine free system in aqueous, micellar medium, can be effectively recovered and reused for subsequent cycles.

Organostannoxane-supported Pd(0) nanoparticles as efficient catalysts for Heck-coupling reactions

A new functional organostannoxane cage, SnP, that contains phosphine ligands in its periphery has been structurally utilized as support palladium(0) nanoparticles SnPPd. The latter was shown to catalyze the Heck coupling reactions of wide variety of functionalities efficiently.

One-pot synthesis of stilbenes by dehydrohalogenation-Heck olefination and multicomponent Wittig-Heck reaction

A variant of olefination reaction involving in situ generation of styrene by either one-pot dehydrohalogenation-Heck or one-pot multicomponent Wittig-Heck reaction is developed.

Heck Reactions under Microwave Irradiation in Solvent-Free Conditions

Palladium-catalyzed vinylation of organic halides can be carried out under microwave irradiation in the absence of solvent in 22 minutes with excellent yields.