273-91-6Relevant articles and documents
Synthesis of 2-Substituted 1,3-Benzoselenazoles from Carboxylic Acids Promoted by Tributylphosphine
Schwartz Radatz, Cátia,Rampon, Daniel S.,Balaguez, Renata A.,Alves, Diego,Schneider, Paulo Henrique
, p. 6945 - 6952 (2016/02/19)
We report a general, practical, and simple metal-free method for the synthesis of 2-substituted 1,3-benzoselenazoles by the reaction of bis(2-aminophenyl)diselenide with a wide range of carboxylic acids, promoted by tributylphosphine. This efficient reaction furnishes 2-aryl-1,3-benzoselenazoles in good yields and tolerates a variety of substituents at the aryl moiety of carboxylic acids. For the first time, 2-alkyl-1,3-benzoselenazoles could be obtained from aliphatic carboxylic acids and thiazolidine-4-carboxylic acid in high chemical yields. The use of focused microwave irradiation considerably decreased the reaction time from 48 to 2 h. The experimental data provide insights into the mechanism of the reaction. A metal-free synthesis of 2-substituted 1,3-benzoselenazoles by the reaction of bis(2-aminophenyl)diselenide with carboxylic acids, promoted by tributylphosphine is reported. For the first time, 2-alkyl-1,3-benzoselenazoles could be obtained from aliphatic carboxylic acids and thiazolidine-4-carboxylic acid in high chemical yields. Microwave irradiation reduced the reaction time.
THE 1,3-BENZOTELLURAZOLE : A NEW HETEROCYCLIC SYSTEM
Mbuyi, Musangu,Evers, Michel,Tihange, Guy,Luxen, Andre,Christiaens, Leon
, p. 5873 - 5876 (2007/10/02)
We describe the synthesis of a new heterocyclic system : the 1,3-benzotellurazole, and some of its substituted derivatives.
Meso-ionic se- and s-containing tetrazoles
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, (2008/06/13)
This invention relates to meso-ionic tetrazole compounds of the formula: STR1 wherein X- is -S- or -Se- which are useful as photographic additives and to an intermediate useful in the preparation thereof having the formula: STR2