27331-43-7

Basic information

• Product Name: Naphthalene, 1-(3-methoxyphenyl)-
• CAS NO: 27331-43-7
• Molecular Formula: C17H14O
• Molecular Weight: 234.298
• Mol File: 27331-43-7.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: Naphthalene, 1-(3-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 1-(3-methoxyphenyl)-(27331-43-7)
• EPA Substance Registry System: Naphthalene, 1-(3-methoxyphenyl)-(27331-43-7)

Safety Data

• Hazardous Substances Data: 27331-43-7(Hazardous Substances Data)

Upstream product

• 36282-40-3 (3-methoxyphenyl)magnesium bromide 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 2398-37-0 3-methoxyphenyl bromide 
• 13922-41-3 1-Naphthylboronic acid 
• 38262-42-9 1-naphthyl mesylate 
• 766-85-8 3-methoxy-1-iodobenzene 
• 90-11-9 1-Bromonaphthalene 
• 31600-88-1 m-methoxyphenyllithium 
• 90-14-2 1-Iodonaphthalene 
• 126485-53-8 (difluoro)(3-methoxyphenyl)(n-propyl)silane 
• 86-56-6 N,N-dimethyl-1-naphthalenamine 
• 1351445-39-0 N,N,N-trimethyl-1-naphthalenaminium trifluoromethanesulfonate 
• 325142-84-5 3-methoxyphenylboronic acid pinacol ester 
• 10365-98-7 3-methoxyphenylboronic acid 

Relevant articles and documents

C(sp2)-C(sp2) Suzuki cross-coupling of arylammonium salts catalyzed by a stable Pd–NHC complex

We have developed the Suzuki-Miyaura cross-coupling of aryl ammonium salts via C–N bond activation catalyzed by an easily prepared and bench-stable palladium-N-heterocyclic carbene complex. The reaction proceeded well under mild conditions with phenylboronic acid, pinacol ester or anhydride and provided yields of products up to 97% with good functional group compatibility. The direct arylation of arylamine can be performed by a two-step one-pot process and the protocol can be performed on the gram scale.

Palladium nanoparticles stabilized by phosphine ligand for aqueous phase room temperature suzuki-Miyaura coupling

Water soluble phosphine ligand triphenylphosphine-3,3′,3″-trisulfonic acid trisodium salt (TPPTS) was used as the stabilizer as well as the activator to the palladium nanoparticles, which showed a high catalytic performance for aqueous phase Suzuki-Miyaura coupling reaction at room temperature.

Oxygen Activated, Palladium Nanoparticle Catalyzed, Ultrafast Cross-Coupling of Organolithium Reagents

The discovery of an ultrafast cross-coupling of alkyl- and aryllithium reagents with a range of aryl bromides is presented. The essential role of molecular oxygen to form the active palladium catalyst was established; palladium nanoparticles that are highly active in cross-coupling reactions with reaction times ranging from 5 s to 5 min are thus generated in situ. High selectivities were observed for a range of heterocycles and functional groups as well as for an expanded scope of organolithium reagents. The applicability of this method was showcased by the synthesis of the [11C]-labeled PET tracer celecoxib.