27634-51-1

Basic information

• Product Name: Ethanone, 1-[4-(1-cyclohexen-1-yl)phenyl]-
• CAS NO: 27634-51-1
• Molecular Formula: C14H16O
• Molecular Weight: 200.28
• Mol File: 27634-51-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-(1-cyclohexen-1-yl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-(1-cyclohexen-1-yl)phenyl]-(27634-51-1)
• EPA Substance Registry System: Ethanone, 1-[4-(1-cyclohexen-1-yl)phenyl]-(27634-51-1)

Safety Data

• Hazardous Substances Data: 27634-51-1(Hazardous Substances Data)

Upstream product

• 13329-40-3 4-Iodoacetophenone 
• 110-83-8 cyclohexene 
• 28075-50-5 cyclohex-1-en-1-yl trifluoromethane sulfonate 
• 149104-90-5 4-acetylphenylboronic acid 
• 108-94-1 cyclohexanone 
• 18594-05-3 4-cyclohexylacetophenone 
• 99-90-1 para-bromoacetophenone 

Downstream Products

• 28164-65-0 β-Methyl-β-[p-(1-cyclohexenyl)-phenyl]-glycidic acid ethyl ester 
• 28168-08-3 1-hydroxy-1-[p-(1-cyclohexenyl)-phenyl]-ethane 

Relevant articles and documents

Visible-Light Photoredox Catalyzed Dehydrogenative Synthesis of Allylic Carboxylates from Styrenes

The visible-light photoredox/[Co(III)] cocatalyzed dehydrogenative functionalization of cyclic and acyclic styryl derivatives with carboxylic acids is documented. The methodology enables the chemo- and regioselective allylic functionalization of styryl compounds, leading to allylic carboxylates (32 examples) under stoichiometric acceptorless conditions. Intermolecular as well as intramolecular variants are documented in high yields (up to 82%). A mechanistic rationale is also proposed on the basis of a combined experimental and spectroscopic investigation.

Heck reaction of aryl halides with linear or cyclic alkenes catalysed by a tetraphosphine/palladium catalyst

cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C 3H5)]2 system catalyses efficiently the Heck reaction of aryl halides with linear alkenes such as pent-1-ene, oct-1-ene or dec-1-ene. Selectivities up to 70% in favour of E-1-arylalk-1-ene isomers can be obtained. In the presence of cyclic alkenes the selectivities of the reactions strongly depends on the ring size. Addition to cyclohexene or cycloheptene led mainly to 1-arylcycloalk-3-ene derivatives. On the other hand, addition to cyclooctene led to 1-arylcycloalk-1-ene adducts.

Tailoring aqueous solvents for organic reactions: Heck coupling reactions in high temperature water

High temperature water is demonstrated to be an effective solvent for Heck coupling reactions of aromatic halides with cyclic alkenes without the addition of co-solvents or specialized ligands. Reactions in the presence of LiCl and quaternary ammonium salts indicate that the reaction takes place in the aqueous phase.