27760-49-2

Basic information

• Product Name: Ethanone, 1-(2-bromophenyl)-, oxime
• CAS NO: 27760-49-2
• Molecular Formula: C8H8BrNO
• Molecular Weight: 214.062
• Mol File: 27760-49-2.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(2-bromophenyl)-, oxime(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2-bromophenyl)-, oxime(27760-49-2)
• EPA Substance Registry System: Ethanone, 1-(2-bromophenyl)-, oxime(27760-49-2)

Safety Data

• Hazardous Substances Data: 27760-49-2(Hazardous Substances Data)

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 
• 2142-69-0 2-bromophenyl methyl ketone 
• 2039-88-5 2-bromostyrene 

Downstream Products

• 79965-72-3 4-(2-bromophenyl)-2-methyloxazole 
• 1613309-60-6 (4R,5S)-diphenylmethyl 1-(diphenylphosphoryl)-5-(2-bromophenyl)-5-methyl-4,5-dihydro-1H-imidazole-4-carboxylate 
• 1613310-11-4 C₁₁H₁₅BrN₂O₂ 
• 1613310-10-3 C₁₀H₁₃BrN₂O₂ 
• 1613309-98-0 (4R,5S)-diphenylmethyl 5-(2-bromophenyl)-5-methyl-4,5-dihydro-1H-imidazole-4-carboxylate 
• 1257846-38-0 8-bromo-1-methyl-3,4-diphenylisoquinoline 
• 1257846-23-3 (E)-1-(2-bromophenyl)ethanone O-acetyl oxime 
• 614-76-6 N-acetyl-2-bromoaniline 
• 113899-55-1 rac-2'-bromo-α-methylbenzylamine 

Relevant articles and documents

Rhodium(III)-Catalyzed Direct C-H Arylation of Various Acyclic Enamides with Arylsilanes

The stereoselective β-C(sp2)-H arylation of various acyclic enamides with arylsilanes via Rh(III)-catalyzed cross-coupling reaction was illustrated. The methodology was characterized by extraordinary efficacy and stereoselectivity, a wide scope of substrates, good functional group tolerance, and the adoption of environmentally friendly arylsilanes. The utility of this present method was evidenced by the gram-scale synthesis and further elaboration of the product. In addition, Rh(III)-catalyzed C-H activation is considered to be the critical step in the reaction mechanism.

Merging alkenyl C-H activation with the ring-opening of 1,2-oxazetidines: Ruthenium-catalyzed aminomethylation of enamides

1,2-Oxazetidines have been utilized as formaldimine precursors for the direct aminomethylation of enamides under a Ru(ii) species. By merging alkenyl C-H activation with ring-opening of 1,2-oxazetidines, this efficient protocol provides a facile and novel

Synthesis of Air- and Moisture-Stable, Storable Chiral Oxorhenium Complexes and Their Application as Catalysts for the Enantioselective Imine Reduction

Air-/moisture-stable, crystalline, and storable chiral salicyloxazoline based oxorhenium(V) complexes have been synthesized and their catalytic application for the asymmetric reduction of ketimines using hydrosilane as hydride source is disclosed. A broad substrate scope, high yields, and excellent enantioselectivities (up to 99 %) are attained. Furthermore, the syntheses of enantiopure α-amino esters, γ- and δ-lactams, and isoindolinones have also been carried out using this methodology. Finally, the method has been applied to synthetic targets of pharmaceutical relevance, such as R-(+)-salsolidine and R-(+)-crispine A.