27871-55-2

Upstream product

• 5027-32-7 1,1,2,2-Tetraacetylethan 
• 123-54-6 acetylacetone 

Downstream Products

• 5027-32-7 1,1,2,2-Tetraacetylethan 
• 27871-59-6 4,4,5,5-tetraacetyl-1,2-dimethylcyclohex-1-ene 
• 121899-34-1 1-(8-Acetyl-7-hydroxy-7-methyl-3-phenyl-1,6-dioxa-2-aza-spiro[4.4]nona-2,8-dien-9-yl)-ethanone 
• 127629-29-2 4-acetyl-2-hydroxy-2,5-dimethyl-2'-phenyl spiro <1.2.4>triazolo-1',3',6'-trione> 
• 127629-33-8 9-acetyl-1,2-di(p-toluoyl)-6,8-dimethyl-6-hydroxy-4-oxa-1,2-diaza spiro<4.4>non-8-ene 
• 92236-52-7 2,6-Dichloro-benzaldehyde O-(3,4-diacetyl-5-hydroxy-2,5-dimethyl-2,5-dihydro-furan-2-yl)-oxime 
• 127629-34-9 9-acetyl-1,2-di(4-chlorobenzoyl)-6,8-dimethyl-6-hydroxy-4-oxa-1,2-diaza spiro<4.4>non-8-ene 
• 116857-85-3 1,3-diphenyl-4,5-diacetylpyrazole 
• 7189-05-1 1-(1,3-diphenyl-1H-pyrazol-4-yl)ethan-1-one 
• 106543-70-8 2,2,4,4,6,6,8,8-Octamethyl-3,7-dioxabicyclo<3.3.0>oct-1(5)-en 
• 116857-90-0 1-(4-methylphenyl)-3-phenyl-4-acetylpyrazole 
• 116857-89-7 1-(4-methylphenyl)-3-phenyl-4,5-diacetylpyrazole 
• 156699-51-3 2,4-Diacetyl-2,5-dimethyl-1-p-tolyl-1,2-dihydro-pyrrol-3-one 
• 156699-49-9 2,4-Diacetyl-1-(4-chloro-phenyl)-2,5-dimethyl-1,2-dihydro-pyrrol-3-one 

Relevant academic research and scientific papers

Tetraacylethenes as dienophiles and hetero dienes in two-step Diels- Alder reactions

Oxidation with barium manganate of the enol of tetraacetylethane (10) affords tetraacetylethylene (7a) in good yield. Treatment of the 1,3- diketones 15a and b with iodosobenzene in the presence of boron trifluoride does not result in oxidative coupling y

Syntheses of Polysubstituted Pyrroles and of 2,3-Disubstituted Quinoxalines and Substituted Benzo[g]quinoxalines

Tetraacetylethylene (1), and cis-diacetylethylene (4) reacted under mild conditions with 3-amino-2-butenoic acid methyl ester (6), benzene-1,2-diamine and naphthalene-2,3-diamine to give polysubstituted pyrroles, 2,3-disubstituted quinoxalines and 2,3-disubstituted benzo[g]quinoxalines respectively. Some aspects of the reactions mechanisms are discussed.

Chemical and Electrochemical Oxidative Dimerization of Carbonyl Compounds by Cerium(IV) Salts. A Comparative Study

β-dicarbonyl and β-cyanocarbonyl compounds were dimerized chemically by CAN or by electrocatalysis using cerous nitrate as mediator.The saturated and unsaturated products of these oxidations are presented.

New cyclohexane- and cyclohexene-1,3-diones from tetraacetylethylene

The new substituted cyclohexane- and cyclohexene-1,3-diones 3-6 and 9, 10, respectively, have been synthesized from tetraacetylethylene 1, through a ring expansion of the cyclopentenone 2.The structures of these products, as well as some features of their