2801-13-0Relevant articles and documents
A CONTROLLED STEPWISE OXIDATION OF ETHYL 2-OXOTHIAZOLIDINE-4-CARBOXYLATE TO THE CORRESPONDING 2-HYDROXYTHIAZOLE
Serra, Gloria,Gonzalez, David,Manta, Eduardo
, p. 2701 - 2712 (2007/10/03)
Methyl 2-hydroxythiazole-4-carboxylate was obtained via a controlled stepwise oxidative procedure from the corresponding 2-oxothiazolidine.A series of intermediates have been isolated and characterized, supporting the ionic and radical mechanisms already proposed in the literature.
SYNTHESIS OF NEW THIOSULFONATES AND DISULFIDES FROM SULFONYL CHLORIDES AND THIOLS
Mahieu, Jean-Pierre,Gosselet, Martine,Sebille, Bernard,Beuzard, Yves
, p. 1709 - 1722 (2007/10/02)
Aromatic thiols were converted into thiosulfonates or disulfides, under very mild conditions, with fair to excellent yields, by using sulfonyl chloride as oxydant reagent.
Acid-catalysed Rearrangement of Bis-5,6-Dihydro-4H-1,3-thiazin-2-yl and Other Disulphides and Related Reactions
Barrett, Anthony G. M.,Barton, Derek H. R.,Colle, Roberto
, p. 665 - 671 (2007/10/02)
Some dithiocarbamates, thiocarbamates, and thiourea derivatives have been oxidised to the disulphides 1X(R2N=)C>2S2 with iodine.In the presence of trifluoroacetic acid, these lost sulphur giving the thiocarbonyl derivatives R1X(R2N=)C-N(R2)CSR1 (R1, R2, X =3, S; 2, S; Me, Me, S; Et, PhCH2, O; 5α-cholestan-3β-yl, Et, O; and Me, Ph, NMe).These rearrangements were most plausibly intramolecular, but proceeded by varying extents of intermolecular scrambling.