281190-31-6Relevant articles and documents
FeCl3 · 6H2O catalyzed disproportionation of allylic alcohols and selective allylic reduction of allylic alcohols and their derivatives with benzyl alcohol
Wang, Jialiang,Huang, Wen,Zhang, Zhengxing,Xiang, Xu,Liu, Ruiting,Zhou, Xigeng
body text, p. 3299 - 3304 (2009/09/08)
Iron chloride has been found to be an efficient catalyst for the disproportionation of allylic alcohols, which provides a convenient method for selective transformation of allylic alcohols to alkenes and α,β- unsaturated ketones. Furthermore, this catalytic system is also effective for highly selective allylic reduction of allylic alcohols, allylic ethers, and allylic acetates with benzyl alcohol under neutral and convenient reaction conditions.
Transetherification of allylic and benzylic ethers in the presence of ferric ion
Salehi, Peyman,Irandoost, Mohsen,Seddighi, Behnam,Kargar Behbahani, Farahnaz,Tahmasebi, Daryush Poor
, p. 1743 - 1747 (2007/10/03)
Alcoholysis of allylic, secondary and tertiary benzylic ethers is proceeded efficiently in the presence of catalytic amounts of ferric ion as anhydrous FeCl3 and Fe(ClO4)3.