28509-24-2Relevant articles and documents
Reactivities of Carbonyl Compounds in Acid-Catalyzed Hydride Transfer vs. Electron Transfer
Fukuzumi, Shunichi,Fujita, Morifumi
, p. 2059 - 2062 (1991)
Rate constants for acid-catalyzed hydride-transfer reactions from triethylsilane to a series of carbonyl compounds are compared with those for acid-catalyzed electron transfer from the excited state of 2+ to the same series of carbonyl compounds in the presence of HClO4 in acetonitrile at 298 K.
Polymer-supported solution synthesis of oligosaccharides
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, (2008/06/13)
The present invention provides improved syntheses of oligosacchairdes. In accordance with preferred embodiments, anomeric specificity in such syntheses can be attained using polymer-supported liquid synthetic design with certain novel diether linkers. The present invention also provides novel strategies for capping imcompletely glycosylated hydroxyls.