286853-92-7

Basic information

• Product Name: (1'''R,2'R,2''R,5'R,5''R)-[5'-(5''-(1'''-tert-butyldimethylsilyloxy-15'''-benzyloxypentadec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]methanol
• Synonyms: (1'''R,2'R,2''R,5'R,5''R)-[5'-(5''-(1'''-tert-butyldimethylsilyloxy-15'''-benzyloxypentadec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]methanol
• CAS NO: 286853-92-7
• Molecular Weight: 619.014
• Mol File: 286853-92-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1'''R,2'R,2''R,5'R,5''R)-[5'-(5''-(1'''-tert-butyldimethylsilyloxy-15'''-benzyloxypentadec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1'''R,2'R,2''R,5'R,5''R)-[5'-(5''-(1'''-tert-butyldimethylsilyloxy-15'''-benzyloxypentadec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]methanol(286853-92-7)
• EPA Substance Registry System: (1'''R,2'R,2''R,5'R,5''R)-[5'-(5''-(1'''-tert-butyldimethylsilyloxy-15'''-benzyloxypentadec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]methanol(286853-92-7)

Safety Data

• Hazardous Substances Data: 286853-92-7(Hazardous Substances Data)

Upstream product

• 286854-02-2 (1R,2'R,2''R,5'R,5''R)-1-[5'-(5''-(tert-butyldimethylsilyloxy)methyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-1-(tert-butyldimethylsilyloxy)-15-benzyloxypentadecan-1-one 

Downstream Products

• 286853-93-8 (1'''R,2'R,2''R,5'R,5''R)-[5-(5'-(1'''-tert-butyldimethylsilyloxy-15'''-benzyloxypentadec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]carbaldehyde 
• 286854-06-6 (2R,5R,2'R,5'R)-5'-[(R)-15-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-pentadecyl]-5-[(1S,5S)-1,5-bis-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl 
• 286854-03-3 (1R,2'R,5'R,2''R,5''R,1'''R,5'''S)-1-[5'-(5''-(1''',5'''-bis(tert-butyldimethylsilyloxy)undec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-1-(tert-butyldimethylsilyloxy)-15-benzyloxypentadecane 
• 247586-74-9 (1S,5S,2'R,5'R,2''R,5''R,1'''R)-1-[5'-(5''-(1'''-tert-butyldimethylsilyloxy-15'''-benzyloxypentadec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-5-(tert-butyldimethylsilyloxy)undecan-1-ol 
• 247586-73-8 (1R,5S,2'R,5'R,2''R,5''R,1'''R)-1-[5'-(5''-(1'''-tert-butyldimethylsilyloxy-15'''-benzyloxypentadec-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-5-(tert-butyldimethylsilyloxy)undecan-1-ol 
• 156199-51-8 asiminacin 
• 120298-30-8 squamocin 

Relevant articles and documents

Total Syntheses of Squamocin A and Squamocin D

The total syntheses of two acetogenins, squamocin A and squamocin D, have been achieved. The adjacent bis-THF subunit was constructed by a multiple Williamson reaction. The left and the right side chain were added by addition of organomagnesium compounds to aldehyde functions. The conversion of a carboxylic acid into the butenolide moiety concluded both syntheses.