Tetrahedron Letters p. 5979 - 5982 (1999)
Update date:2022-08-04
Topics:
Emde, Ulrich
Koert, Ulrich
The total syntheses of two acetogenins, squamocin A and squamocin D, have been achieved. The adjacent bis-THF subunit was constructed by a multiple Williamson reaction. The left and the right side chain were added by addition of organomagnesium compounds to aldehyde functions. The conversion of a carboxylic acid into the butenolide moiety concluded both syntheses.
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