28713-50-0Relevant articles and documents
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Lalancette,J.M.,Freche,A.
, p. 4047 - 4053 (1971)
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A new strategy for chemoselective O-acylation of β-mercapto alcohols via alkylsilyl and stannyl protection
Maheswara, Muchchintala,Kim, Mirae,Yun, Sun-Ju,Ju, Jung Jin,Do, Jung Yun
scheme or table, p. 480 - 483 (2009/05/07)
Chemoselective preparation of O-acylated derivatives from bis-protected mercapto alcohols was described. Trialkylsilyl and trialkylstannyl chloride are used to generate an intermediate with O- and S-protection. The intermediates from β-mercapto alcohols a
Synthesis of thiols via palladium catalyzed methanolysis of thioacetates with borohydride exchange resin
Choi,Yoon
, p. 2655 - 2663 (2007/10/02)
Various thiols are prepared quantitatively from the corresponding thioacetates via Pd catalyzed methanolysis with borohydride exchange resin under a mild and neutral conditions. One-pot synthesis of thiols from alkyl halides through the formation of alkyl thioacetates using thioacetate exchange resin followed by methanolysis is also described.