28720-93-6Relevant academic research and scientific papers
Copper-catalyzed regioselective allylic oxidation of olefins via C–H activation
Zhu, Nengbo,Qian, Bo,Xiong, Haigen,Bao, Hongli
supporting information, p. 4125 - 4128 (2017/09/29)
A regioselective oxidation of allylic C–H bond to C–O bond catalyzed by copper (I) was developed with diacyl peroxides as oxidants. The oxidation of allylic C–H bond was accomplished with good yield and regioselectivity under mild reaction conditions. This method has a broad substrate scope including cyclic olefins, terminal and internal acyclic olefins and allyl benzene compounds. The reaction proceeds by a radical mechanism as suggested by spin trapping experiments.
