28781-91-1

Basic information

• Product Name: 1,1,2,2,3,3-Propanehexacarboxylic acid, hexamethyl ester
• CAS NO: 28781-91-1
• Molecular Formula: C15H20O12
• Molecular Weight: 392.317
• Mol File: 28781-91-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,1,2,2,3,3-Propanehexacarboxylic acid, hexamethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,2,2,3,3-Propanehexacarboxylic acid, hexamethyl ester(28781-91-1)
• EPA Substance Registry System: 1,1,2,2,3,3-Propanehexacarboxylic acid, hexamethyl ester(28781-91-1)

Safety Data

• Hazardous Substances Data: 28781-91-1(Hazardous Substances Data)

Upstream product

• 868-26-8 dimethyl 2-bromomalonate 
• 108-59-8 malonic acid dimethyl ester 
• 67-56-1 methanol 

Downstream Products

• 99-14-9 tricarallylic acid 
• 124-38-9 carbon dioxide 
• 109777-05-1 hexanethyl ester of cyclopropanehexacarboxylic acid 
• 133455-79-5 Hexamethyl ester of 1-bromopropane-1,1,2,2,3,3-hexacarboxylic acid 
• 110622-29-2 tetramethyl ester of 1-methoxyethane-1,1,2,2-tetracarboxylic acid 
• 113563-33-0 tetramethyl ester of 1-bromo-2-methoxyethanetetracarboxylic acid 
• 1733-15-9 Tetramethyl ethylenetetracarboxylate 

Relevant articles and documents

Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators

Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides follows two different pathways depending on the nature of the cation. In the presence of LiI, alkyl 1,1,2,2,3,3-propanetetracarboxylates were obtained in 85-98% yields. In the presence of NaI, KI, or Bu4NI, the formation of 1,1,2,2-ethanetetracarboxylates and their subsequent dehydrogenation to ethenetetracarboxylates was the main reaction pathway.

ELECTROCHEMICAL OXIDATION OF MALONIC ESTERS IN THE PRESENCE OF CATALYST CARRIERS - SALTS OF HYDRIODIC ACID

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