287922-84-3

Upstream product

• 100-52-7 benzaldehyde 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 183388-21-8 allyl 4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 

Downstream Products

• 869201-28-5 allyl 3,6-di-O-benzyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranoside 
• 391860-83-6 2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester 
• 1058623-95-2 C₂₅H₂₄Cl₆N₂O₇ 
• 1262956-60-4 C₂₆H₃₀Cl₃NO₇ 
• 1262956-61-5 C₂₆H₂₈Cl₃NO₇ 
• 287922-83-2 (R)-3-(4-Trifluoromethyl-benzyloxy)-octadecanoic acid ((2S,3R,4R,5S,6R)-2-allyloxy-4,5-bis-benzyloxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-amide 
• 287922-86-5 2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester 
• 287922-87-6 ((2S,3R,4R,5S,6R)-2-Allyloxy-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-tetrahydro-pyran-3-yl)-carbamic acid 2,2,2-trichloro-ethyl ester 
• 1025449-61-9 allyl-2-amino-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 287922-85-4 allyl-3,4-di-O-benzyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside 

Relevant academic research and scientific papers

Synthetic study of peptidoglycan partial structures. Synthesis of tetrasaccharide and octasaccharide fragments

Partial structures of peptidoglycan, a potent immunostimulating glycoconjugate of bacteria, were synthesized for precise biological studies. A key disaccharide glucosaminyl-β(1-4)-muramic acid was prepared by stereoselective glycosylation of a N-Troc (Tro

Towards glucosamine building blocks: Regioselective one-pot protection and deallylation procedures

Glucosamine building blocks have been prepared by an efficient regioselective one-pot protection approach. This synthetic route enabled the straightforward preparation of a glucosamine disaccharide in 73% yield. The system Pd(PPh3)4/

Functionalized Beta 1,6 Glucosamine Disaccharides and Process for Their Preparation

The present invention relates to a novel process for the chemical synthesis of β-(1->6)-linked glucosamine disaccharides of the formula (1) and (intermediate) compounds relating to the process. According to further aspects the invention relates to composi

Synthesis of Helicobacter pylori lipid A and its analogue using p-(trifluoromethyl)benzyl protecting group

Synthesis of lipid A 1 isolated from Helicobacter pylori strain-206-1 has been achieved in 2.2% total yield through 14 steps from D-glucosamine by employing a p-(trifluoromethyl)benzyl group for protection of the hydroxy group on the 3-hydroxy fatty acid residue. The synthetic specimen was identical with the natural counterpart in chromatographic, spectroscopic, and biological aspects. A structural analogue 2 which lacks the ethanolamine residue of 1 was also synthesized, and 2 was found to exhibit less potent IL-1β-inducing activity than 1. (C) 2000 Elsevier Science Ltd.