287922-85-4

Upstream product

• 183388-21-8 allyl 4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 287922-84-3 allyl 3-O-benzyl-4,6-O-benzylidene-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside 

Downstream Products

• 287922-87-6 ((2S,3R,4R,5S,6R)-2-Allyloxy-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-tetrahydro-pyran-3-yl)-carbamic acid 2,2,2-trichloro-ethyl ester 
• 1351706-71-2 C₅₈H₆₄Cl₃NO₁₄ 
• 1025449-61-9 allyl-2-amino-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 287922-83-2 (R)-3-(4-Trifluoromethyl-benzyloxy)-octadecanoic acid ((2S,3R,4R,5S,6R)-2-allyloxy-4,5-bis-benzyloxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-amide 
• 287922-86-5 2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester 

Relevant academic research and scientific papers

Functionalized Beta 1,6 Glucosamine Disaccharides and Process for Their Preparation

The present invention relates to a novel process for the chemical synthesis of β-(1->6)-linked glucosamine disaccharides of the formula (1) and (intermediate) compounds relating to the process. According to further aspects the invention relates to composi

Efficient procedure for reductive opening of sugar 4,6-O-benzylidene acetals in a microfluidic system

An efficient procedure for the reductive opening of 4,6-O-benzylidene acetals was established under microfluidic conditions. 4,6-O-Benzylidene acetals of the glucose, glucosamine, and galactose derivatives were selectively converted into the corresponding

Synthesis of Helicobacter pylori lipid A and its analogue using p-(trifluoromethyl)benzyl protecting group

Synthesis of lipid A 1 isolated from Helicobacter pylori strain-206-1 has been achieved in 2.2% total yield through 14 steps from D-glucosamine by employing a p-(trifluoromethyl)benzyl group for protection of the hydroxy group on the 3-hydroxy fatty acid residue. The synthetic specimen was identical with the natural counterpart in chromatographic, spectroscopic, and biological aspects. A structural analogue 2 which lacks the ethanolamine residue of 1 was also synthesized, and 2 was found to exhibit less potent IL-1β-inducing activity than 1. (C) 2000 Elsevier Science Ltd.