28953-96-0

Basic information

• Product Name: 1-chloro-2-isopropyl-5-methylcyclohexane
• Synonyms: 1-chloro-2-isopropyl-5-methylcyclohexane;2-Chloro-4-methyl-1-(1-methylethyl)cyclohexane
• CAS NO: 28953-96-0
• Molecular Formula: C₁₀H₁₉Cl
• Molecular Weight: 174.71086
• EINECS: 249-326-7
• Mol File: 28953-96-0.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 216.1°Cat760mmHg
• Flash Point: 78.9°C
• Appearance: /
• Density: 0.92g/cm³
• CAS DataBase Reference: 1-chloro-2-isopropyl-5-methylcyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-2-isopropyl-5-methylcyclohexane(28953-96-0)
• EPA Substance Registry System: 1-chloro-2-isopropyl-5-methylcyclohexane(28953-96-0)

Safety Data

• Hazardous Substances Data: 28953-96-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H19Cl/c1-7(2)9-5-4-8(3)6-10(9)11/h7-10H,4-6H2,1-3H3

Upstream product

• 77774-21-1 l-(-)-(Menthyloxy)triphenylphosphonium triflate 
• 2216-51-5 (-)-menthol 
• 15356-60-2 (1S,2R,5S)-(+)-menthol 
• 7647-01-0 hydrogenchloride 
• 6308-42-5 p-menthan-3-yl-hydrazine 
• 7758-99-8 copper(II) sulfate 
• 89-78-1 menthol 

Downstream Products

• 54556-12-6 2-isopropyl-5-methyl-cyclohexanecarbonitrile 
• 99-82-1 Menthane 
• 39668-86-5 menthanecarboxylic acid 
• 41437-76-7 3-(p'-Isopropylbenzyl)-p-menthan 
• 133490-07-0 menthyl isothiocyanate 
• 133490-06-9 1-Isopropyl-4-methyl-2-thiocyanato-cyclohexane 
• 500-00-5 3-p-menthene 
• 54556-65-9 N,3-Diethyl-p-menthan-3-carboxamid 
• 1845-44-9 2-isopropyl-5-methyl-cyclohexanecarbaldehyde 
• 137724-75-5 1-Menthyl cation 
• 41437-75-6 3-Benzyl-p-menthan 

Relevant articles and documents

NMP-mediated chlorination of aliphatic alcohols with aryl sulfonyl chloride for the synthesis of alkyl chlorides

NMP-mediated chlorination of aliphatic alcohols has been developed for the synthesis of alkyl chlorides. This facile, efficient and practical approach used simple and readily available aryl sulfonyl chlorides as the chlorination reagent for the construction of C–Cl bond in good to excellent yields with mild conditions and broad substrate scope.

A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions

A mild method for the facile removal of phosphine oxide from the crude products of Wittig and Appel reactions is described. Work-up with oxalyl chloride to generate insoluble chlorophosphonium salt (CPS) yields phosphorus-free products for a wide variety of these reactions. The CPS product can be further converted into phosphine.

Reactivity of bismuth(III) halides towards alcohols. A tentative to mechanistic investigation

The reactivity of bismuth(III) halides (BiX3; X=Cl, Br and I) towards a series of alcohols has been investigated. Three different reactions have been studied, namely: halogenation, dehydration and etherification. The behaviour of these bismuth derivatives was found to depend on the nature of the halide bonded to the bismuth atom. Their reactivities can be interpreted on the basis of the Hard and Soft Acids and Bases (HSAB) principle. A mechanism is proposed which involves the formation of a complex of the alcohol with Bi(III).