289680-83-7

Basic information

• Product Name: 1-chloro-4-phenyl-1-(p-tolylsulfinyl)-2-butanol
• Synonyms: 1-chloro-4-phenyl-1-(p-tolylsulfinyl)-2-butanol
• CAS NO: 289680-83-7
• Molecular Weight: 322.856
• Mol File: 289680-83-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-chloro-4-phenyl-1-(p-tolylsulfinyl)-2-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-4-phenyl-1-(p-tolylsulfinyl)-2-butanol(289680-83-7)
• EPA Substance Registry System: 1-chloro-4-phenyl-1-(p-tolylsulfinyl)-2-butanol(289680-83-7)

Safety Data

• Hazardous Substances Data: 289680-83-7(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 24824-93-9 chloromethyl p-tolyl sulfoxide 

Downstream Products

• 40463-09-0 4-methyl-1-phenylpentan-3-one 
• 5195-30-2 3-methyl-5-phenyl-2-pentanone 
• 224319-37-3 (E)-1-chloro-4-phenyl-1-(p-tolylsulfinyl)-1-butene 
• 224319-35-1 (Z)-1-chloro-4-phenyl-1-(p-tolylsulfinyl)-1-butene 
• 2550-26-7 4-Phenyl-2-butanone 

Relevant articles and documents

Reaction of 1-chlorovinyl p-tolyl sulfoxides with carbanion of acetonitrile: A novel synthesis of cyclopentanone derivatives with three consecutive carbon-carbon bond-formations via the enaminonitriles

Treatment of 1-chlorovinyl p-tolyl sulfoxides derived from ketones with cyanomethyllithium gave cyclopentadienyl enaminonitriles in high yields with three consecutive carbon- carbon bond-formations. However, the 1-chlorovinyl p-tolyl sulfoxides derived from aldehydes did not give good results. The mechanism of this reaction and the reaction of the enaminonitriles to convert cyclopentanone derivatives were investigated. Several α-carbanion of nitriles other than acetonitrile added to the 1-chlorovinyl p-tolyl sulfoxides at low temperature in good yield; however, they did not cyclize upon warming to room temperature. (C) 2000 Elsevier Science Ltd.