29024-77-9Relevant academic research and scientific papers
Oxidation of 2,4-dinitrotoluene with ozone in the presence of a stop reagent
Galstyan,Lysak,Galstyan
, p. 31 - 35 (2014/05/06)
Liquid-phase oxidation of 2,4-dinitrotoluene with ozone in the presence of acetic anhydride as stop reagent and manganese(II) acetate as catalyst was studied. The major products of oxidation with ozone in acetic anhydride are 2,4-dinitrobenzyl alcohol (65.8%) and 2,4-dinitrobenzaldehyde (18.8%) in the form of the corresponding acetates. A reaction scheme accounting for the results obtained is considered. Pleiades Publishing, Ltd., 2014.
Kinetics and mechanism of the liquid-phase reaction of 2,4-dinitrotoluene with ozone in the presence of manganese(II) acetate
Galstyan,Lysak,Galstyan
, p. 686 - 690 (2014/01/23)
The kinetics and the mechanism of the liquid-phase oxidation of 2,4-dinitrotoluene with ozone in the presence of manganese(II) acetate have been investigated. The major products of 2,4-dinitrotoluene oxidation with ozone in acetic anhydride are 2,4-dinitrobenzyl acetate (65.8%) and 2,4- dinitrobenzylidene diacetate (18.8%). The effect of the manganese(II) acetate concentration on the selectivity of substrate oxidation at the methyl group is reported. A redox catalysis mechanism providing an explanation to experimental data is considered. Pleiades Publishing, Ltd., 2013.
