290822-91-2

Basic information

• Product Name: 6-O-benzyl-1-deoxy-1-dimethylphosphono-3,4-O-isopropylidene-D-allose
• Synonyms: 6-O-benzyl-1-deoxy-1-dimethylphosphono-3,4-O-isopropylidene-D-allose
• CAS NO: 290822-91-2
• Molecular Weight: 404.397
• Mol File: 290822-91-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-O-benzyl-1-deoxy-1-dimethylphosphono-3,4-O-isopropylidene-D-allose(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-benzyl-1-deoxy-1-dimethylphosphono-3,4-O-isopropylidene-D-allose(290822-91-2)
• EPA Substance Registry System: 6-O-benzyl-1-deoxy-1-dimethylphosphono-3,4-O-isopropylidene-D-allose(290822-91-2)

Safety Data

• Hazardous Substances Data: 290822-91-2(Hazardous Substances Data)

Upstream product

• 290822-88-7 (-)-1-deoxy-1-(dimethylphosphono)-3,4-O-isopropylidene-D-ribo-hexofuranose 
• 30725-00-9 2,3-O-isopropylidene-D-ribonic-γ-lactone 
• 117251-95-3 Dimethyl (6-O-benzyl-1-deoxy-3,4-O-isopropylidene-β-D-ribo-hex-2-ulofuranosyl)phosphonate 

Downstream Products

• 290823-01-7 (1S,2S,3S,4S,5S)-(-)-4-(6-amino-purin-9-yl)-1-benzyloxymethyl-6-oxa-bicyclo[3.1.0]hexane-2,3-diol 
• 290823-00-6 (1R,2S,3S,4S,5R)-(-)-4-(6-amino-purin-9-yl)-1-benzyloxymethyl-6-oxa-bicyclo[3.1.0]hexane-2,3-diol 
• 290822-99-0 (1S,2S,3S,4S,5S)-(-)-1-benzyloxymethyl-4-(6-chloropurin-9-yl)-6-oxa-bicyclo[3.1.0]hexane-2,3-diol 
• 290822-98-9 (1R,2S,3S,4S,5R)-(-)-1-benzyloxymethyl-4-(6-chloropurin-9-yl)-6-oxa-bicyclo[3.1.0]hexane-2,3-diol 
• 290822-97-8 (-)-9-[(1R,4R,5S)-3-(benzyloxy)methyl-4,5-dihydroxycyclopent-2-en-1-yl]-6-chloropurine 
• 89291-74-7 (3R,4R)-(-)-6-O-benzyl-1-deoxy-1-(dimethylphosphono)-3,4-O-isopropylidene-D-erythro-2,5-hexodiulose 
• 89291-81-6 (-)-9-<(1R,4R,5S)-3-<(benzyloxy)methyl>-4,5-O-isopropylidene-2-cyclopenten-1-yl>-6-chloropurine 
• 117307-62-7 (3aR,6aR)-6-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-one 
• 89291-76-9 (1S,4R,5S)-(-)-3-<(benzyloxy)methyl>-4,5-O-isopropylidene-2-cyclopenten-1-ol 

Relevant articles and documents

First synthesis of (-)-neplanocin C

(-)-Neplanocin C (4), a minor component of the neplanocin family of antibiotics and a lead drug for the design of several conformationally constrained nucleosides analogues, was enantioselectively synthesized starting from D-ribono-1,4-lactone via a convergent approach in twelve steps. The proton NMR spectrum of 4 was in agreement with the corresponding natural product. Calculated coupling constants obtained from ab initio molecular modeling studies and from previously published X-ray structure of neplanocin C also corresponded to the spectroscopic data. (C) 2000 Elsevier Science Ltd.