291314-82-4

Basic information

• Product Name: 3-Buten-2-ol, 4-(4-methoxyphenyl)-, acetate, (2R,3E)-
• CAS NO: 291314-82-4
• Molecular Formula: C13H16O3
• Molecular Weight: 220.268
• Mol File: 291314-82-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-Buten-2-ol, 4-(4-methoxyphenyl)-, acetate, (2R,3E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-2-ol, 4-(4-methoxyphenyl)-, acetate, (2R,3E)-(291314-82-4)
• EPA Substance Registry System: 3-Buten-2-ol, 4-(4-methoxyphenyl)-, acetate, (2R,3E)-(291314-82-4)

Safety Data

• Hazardous Substances Data: 291314-82-4(Hazardous Substances Data)

Upstream product

• 876-27-7 4-chlorophenyl acetate 
• 32271-54-8 (E)-1-(4-methoxyphenyl)pent-1-en-3-ol 
• 108-05-4 vinyl acetate 
• 108-22-5 Isopropenyl acetate 
• 3815-30-3 4-(4-methoxyphenyl)-3-buten-2-one 
• 140846-38-4 1-(4-methoxyphenyl)-2-buten-1-ol 
• 140846-38-4 (E)-1-(4-methoxyphenyl)-2-buten-1-ol 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 1963-36-6 4-methoxycinnamaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 1027314-32-4 Toluene-4-sulfonic acid (E)-(S)-3-(4-methoxy-phenyl)-2-methyl-hex-4-enyl ester 
• 675831-36-4 (3R)-trans-3-(4-methoxyphenyl)-2-methylhex-4-enoic acid 
• 675831-37-5 (R)-trans-1-(1-isopropylbut-2-enyl)-4-methoxybenzene 
• 675831-39-7 (S)-1-[1-(bromomethyl)-2-methylpropyl]-4-methoxybenzene 
• 675831-38-6 (2S)-2-(4-methoxyphenyl)-3-methylbutan-1-ol 
• 309271-62-3 (S)-4-(4-methoxyphenyl)-5-methylhexanoic acid 
• 174174-00-6 (+)-(2R,3E)-4-(4'-methoxyphenyl)but-3-en-2-ol 

Relevant articles and documents

Continuous-Flow Dynamic Kinetic Resolution of Racemic Alcohols by Lipase–Oxovanadium Cocatalysis

A continuous-flow dynamic kinetic resolution of racemic secondary alcohols was carried out using a single column reactor packed with a mixture of immobilized lipase and an immobilized oxovanadium species, VMPS4. As a result, optically pure esters were produced in 88–92 % yields. Problems encountered in this study were overcome by using fillers that efficiently maintained the initial distribution of the catalysts in the reactor and by using a packing method in which the mixing ratio of the two catalysts was varied in a stepwise fashion. The flow process led to an increased turnover number of each catalyst compared to those of batch reactions.

Enantioselective synthesis of cis-7-methoxy-calamenene via Claisen rearrangement of an enzymatically resolved allyl alcohol

An enantioselective synthesis of cis-7-methoxy-calamenene 1 has been accomplished through the following key-steps: (i) enzymatic resolution of the racemic allyl alcohol 3 to furnish the (R)-enantiomer (ee>99%); (ii) Claisen-orthoester rearrangement of 4 t

Dynamic kinetic resolution of allylic alcohols mediated by ruthenium- and lipase-based catalysts.

An enzyme-metal combo reaction has been developed for the dynamic kinetic resolution of allylic alcohols in which racemic substrates are transformed by a lipase and a ruthenium complex in the presence of an acyl donor to allylic acetates of high optical purity in over 80% yield.