292631-98-2Relevant academic research and scientific papers
Acid-catalyzed synthesis of bicyclo[3. n.1]alkenediones
Michaelides, Iacovos N.,Darses, Benjamin,Dixon, Darren J.
supporting information; experimental part, p. 664 - 667 (2011/04/24)
An acid-catalyzed Dieckmann-type reaction has been developed to access functionalized bicyclo[3.2.1]alkenediones. This methodology has been successfully extended to more substituted and larger ring homologues, providing a new and efficient route to the core of numerous attractive natural products and their analogues.
Pd-catalyzed sulfinylzincation of activated alkynes with 1-alkynyl sulfoxides as a sulfinyl source
Maezaki, Naoyoshi,Yagi, Suguru,Yoshigami, Ryoko,Maeda, Jun,Suzuki, Tomoko,Ohsawa, Shizuka,Tsukamoto, Kouji,Tanaka, Tetsuaki
, p. 5550 - 5558 (2007/10/03)
Unprecedented Pd-catalyzed sulfinylzincation with 1-alkynyl sulfoxide as a sulfinyl source was developed. Bis-sulfinyl alkenes were formed in good yields on treatment of 1-alkynyl sulfoxides with Et2Zn in the presence of a Pd-catalyst, wherein
Use of π-allyltricarbonyliron lactone complexes in the synthesis of taurospongin A: A potent inhibitor of DNA polymerase β and HIV reverse transcriptase
Hollowood, Christopher J.,Yamanoi, Shigeo,Ley, Steven V.
, p. 1664 - 1675 (2007/10/03)
The total synthesis of taurospongin A by two new approaches has been achieved where π-allyltricarbonyliron lactone complexes have been used to control highly stereoselective additions of the nucleophiles to a carbonyl unit located in the side chain of the
Enantioselective synthesis of (2S,3R)-3-hydroxy-3-methylproline, a novel amino acid found in polyoxypeptins
Qin, Dong-Guang,Zha, Hui-Yan,Yao, Zhu-Jun
, p. 1038 - 1040 (2007/10/03)
The enantioselective synthesis of (2S,3R)-3-hydroxy-3-methylproline (3) was achieved by the Sharpless AD, regioselective opening of cyclic sulfate by NaN3 and intramolecular ring-closing reaction. The reported route has the advantage of a high
