2928-09-8

Basic information

• Product Name: Benzoic acid, 4-fluoro-, 1-Methylethyl ester
• Synonyms: Benzoic acid, 4-fluoro-, 1-Methylethyl ester
• CAS NO: 2928-09-8
• Molecular Formula: C₁₀H₁₁FO₂
• Molecular Weight: 182.1915432
• EINECS: -0
• Mol File: 2928-09-8.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzoic acid, 4-fluoro-, 1-Methylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-fluoro-, 1-Methylethyl ester(2928-09-8)
• EPA Substance Registry System: Benzoic acid, 4-fluoro-, 1-Methylethyl ester(2928-09-8)

Safety Data

• Hazardous Substances Data: 2928-09-8(Hazardous Substances Data)

Upstream product

• 67-63-0 isopropyl alcohol 
• 579-39-5 1,2-bis(4-fluorophenyl)ethane-1,2-dione 
• 546-68-9 titanium(IV)isopropoxide 
• 456-22-4 4-Fluorobenzoic acid 
• 459-57-4 4-fluorobenzaldehyde 
• 22913-11-7 isopropyl 4-chlorobenzoate 
• 75-57-0 tetramethlyammonium chloride 
• 403-43-0 4-fluorobenzoyl chloride 

Downstream Products

• 1356411-39-6 2-propyl 4-(aminoxy)benzoate 
• 401925-43-7 isopropyl 2-butyl-3-{4-[3-(dibutylamino)propyl]benzoyl}-1-benzofuran-5-carboxylate 
• 459-57-4 4-fluorobenzaldehyde 

Relevant articles and documents

Nickel-Catalyzed Esterification of Amides Under Mild Conditions

Abstract: The use of ligands to adjust the catalytic activity of the catalyst for esterification of amides is challenge in organic chemistry. In this paper, Nickel(II)-NHC-catalyzed the esterification reaction between N,N-di-Boc amide and alcohols at room temperature have been demonstrated. The imidazolium salt bearing a hydroxyl functionalized side arm showed high effective catalytic activity in the activation of the amide N–C bond in air atmosphere. Graphic Abstract: [Figure not available: see fulltext.].

Synthesis and characterization of stable ZnO nanoparticles using imidazolium-based ionic liquids and their applications in esterification reaction

ZnO nanoparticles have been synthesized from zinc acetate using 1-octyl-3-methylimidazolium hexafluorophosphate as capping agent under microwave irradiation condition in a very short period of time and characterized using UV-visible spectroscopy, powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy and NH3-TPD analysis. The ZnO NPs have been used as a solid reusable acid catalyst for esterification of carboxylic acids with alcohols.

Pd-catalyzed aldehyde to ester conversion: A hydrogen transfer approach

Aliphatic and aromatic aldehydes are successfully converted into their corresponding esters using Pd(OAc)2 and XPhos. This approach utilizes a hydrogen transfer protocol: concomitant reduction of acetone to isopropanol provides an inexpensive and sustainable approach that mitigates the need for other oxidants.