2943-26-2

Basic information

• Product Name: S-benzyl O-ethylxanthate
• Synonyms: S-benzyl O-ethylxanthate
• CAS NO: 2943-26-2
• Molecular Weight: 212.337
• Mol File: 2943-26-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: S-benzyl O-ethylxanthate(CAS DataBase Reference)
• NIST Chemistry Reference: S-benzyl O-ethylxanthate(2943-26-2)
• EPA Substance Registry System: S-benzyl O-ethylxanthate(2943-26-2)

Safety Data

• Hazardous Substances Data: 2943-26-2(Hazardous Substances Data)

Upstream product

• 140-89-6 potassium ethyl xanthogenate 
• 100-39-0 benzyl bromide 
• 94442-87-2 S-Phenylacetyl-xanthogensaeure 
• 100-44-7 benzyl chloride 
• 623-79-0 O,S-Diethyl dithiocarbonate 
• 75-15-0 carbon disulfide 
• 64-17-5 ethanol 

Downstream Products

• 100-53-8 phenylmethanethiol 
• 588-59-0 stilbene 
• 108-88-3 toluene 
• 75-15-0 carbon disulfide 
• 71-43-2 benzene 
• 64-17-5 ethanol 
• 541-41-3 chloroformic acid ethyl ester 
• 1939-99-7 benzenesulfonyl chloride 
• 37734-45-5 benzyl chlorothioformate 
• 1415355-15-5 o-ethyl s-3-phenyl-1-phthalimidomethylpropyl dithiocarbonate 
• 1415355-24-6 4-phenyl-1-phthalimidobutane-2-sulfonic acid 
• 1415355-35-9 1-amino-4-phenylbutane-2-sulfonic acid 
• 998-98-1 N-ethyl O-ethyl thiocarbamate 
• 60789-51-7 benzyl(4-nitro-2-(trifluoromethyl)phenyl)sulfane 

Relevant articles and documents

A Novel Method for the Direct Synthesis of Symmetrical and Unsymmetrical Sulfides and Disulfides from Aryl Halides and Ethyl Potassium Xanthogenate

An efficient and new method for the synthesis of disulfides and sulfides via the reaction of aryl halides with ethyl potassium xanthogenate in the presence of MOF-199 is described. O -Ethyl- S -aryl carbonodithioate has a key role as an intermediate in this procedure; it was converted into symmetrical diaryl disulfides in DMF. Additionally, this could be applied to the synthesis of unsymmetrical aryl alkyl(aryl′) disulfides by the reaction with S -alkyl(aryl) sulfurothioates (Bunte salts) as well as unsymmetrical aryl alkyl(aryl′) sulfides in DMSO.

S-alkyl chlorothioformates from xanthates

Reaction of S-alkyl O-ethyl xanthates (S-alkyl O-ethyl dithiocarbonates) with catalytic Vilsmeier reagent generated in situ from N-formylmorpholine (morpholine-4-carbaldehyde) gives S-alkyl chlorothioformates in good yields. Georg Thieme Verlag Stuttgart.