29556-28-3Relevant academic research and scientific papers
Synthesis, crystal structure, spectroscopic properties, DFT calculation and biological activity of 4-chloro-N-(2-(2-nitrophenyl)acetoxy)-N-phenylbenzamide
He, Dian,Yang, Zhu-Qing,Hou, Meng,Teng, Chong,Wang, Xiao-Hong
, p. 730 - 736 (2014)
4-Chloro-N-(2-(2-nitrophenyl)acetoxy)-N-phenylbenzamide was synthesized and characterized by 1H NMR, 13C NMR, MS, IR and X-ray diffraction methods. The structure-property relationship and the antitumor activity based on electrochemic
Facile access to amides and hydroxamic acids directly from nitroarenes
Jain, Shreyans K.,Aravinda Kumar,Bharate, Sandip B.,Vishwakarma, Ram A.
, p. 6465 - 6469 (2014/08/18)
A new method for synthesis of amides and hydroxamic acids from nitroarenes and aldehydes is described. The MnO2 catalyzed thermal deoxygenation of nitrobenzene resulted in formation of a reactive nitroso intermediate which on reaction with aldehydes provided amides and hydroxamic acids. The thermal neat reaction in the presence of 0.01 mmol KOH predominantly led to formation of hydroxamic acid whereas reaction in the presence of 1 mmol acetic acid produced amides as the only product. the Partner Organisations 2014.
N-heterocyclic-carbene-catalyzed one-pot synthesis of hydroxamic esters
Song, Xiaoxiao,Ni, Qijian,Grossmann, Andre,Enders, Dieter
supporting information, p. 2965 - 2969 (2014/01/06)
The honey pot: The NHC-catalyzed reaction between nitrosobenzenes, aromatic/aliphatic aldehydes, and enals proceeded through an aza-benzoin-type reaction and an internal redox esterification to afford hydroxamic esters in good yields. Copyright
Solid-phase extraction of plutonium(IV) an americium(III) using N-benzoylphenylhydroxylamine and its derivatives
Petrukhin,Spivakov,Morgalyuk,Malofeeva,Kuzovkina,Novikov
experimental part, p. 1839 - 1846 (2012/01/31)
The recovery and separation of plutonium(IV) and americium(III) by solid-phase extraction (SPE) on alkylated silica gel S16 modified with N-benzoylphenylhydroxylamine (BPHA) and with its derivatives was studied. BPHA was modified by introducing into the p-position of the phenyl ring of electronactive substituents that differ in their hydrophobicity: CH3, Ph, Cl, F, and NO2. The SPE of plutonium(IV) and americium(III) was studied in the range of acidities from pH 8 to 1 M HNO3. The recovery and separation of these elements was shown to depend on the nature of the substituent, aqueous acidity, and the preparation of S16 to SPE experiments.
