2978-29-2

Basic information

• Product Name: N-(prop-2-en-1-yl)butanamide
• Synonyms: N-(prop-2-en-1-yl)butanamide
• CAS NO: 2978-29-2
• Molecular Weight: 127.186
• Mol File: 2978-29-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(prop-2-en-1-yl)butanamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(prop-2-en-1-yl)butanamide(2978-29-2)
• EPA Substance Registry System: N-(prop-2-en-1-yl)butanamide(2978-29-2)

Safety Data

• Hazardous Substances Data: 2978-29-2(Hazardous Substances Data)

Upstream product

• 920-39-8 isopropylmagnesium bromide 
• 57-06-7 N-allyl isothiocyanate 
• 1283075-90-0 dipropan-2-yl 1-butanoylhydrazine-1,2-dicarboxylate 
• 107-11-9 1-amino-2-propene 

Downstream Products

• 10264-14-9 N-benzylbutyramide 

Relevant articles and documents

Cp2TiCl2-CATALYZED REACTION OF GRIGNARD REAGENTS WITH ISOCYANATES, FORMATION OF CARBOXAMIDE WITH REARRANGED CARBONSKELETON

Isocyanates react with isopropyl or sec-butylmagnesium bromide in the presence of a small amount of Cp2TiCl2 to afford amides with normal alkyl group.A possibl mechanism for this reaction is proposed.

Functionalisation of aldehydes via aerobic hydroacylation of azodicarboxylates 'on' water

Herein we report the functionalisation of aldehydes via hydroacylation of azodicarboxylates. A range of functionalised aldehydes are employed as the limiting reagent including chiral non-racemic aldehydes bearing α-stereocentres which are functionalised giving access to enantiomerically pure products. The resultant hydrazides can be employed as acyl donors in the synthesis of amides.