Cp2TiCl2-CATALYZED REACTION OF GRIGNARD REAGENTS WITH ISOCYANATES, FORMATION OF CARBOXAMIDE WITH REARRANGED CARBONSKELETON

DOI: 10.1016/S0040-4039(00)96392-5

Source and publish data:

Tetrahedron Letters p. 3815 - 3816 (1987)

Update date:2022-07-30

Topics:

Authors:

Zhang, Yongmin

Jiang, Jinlong

Chen, Yongqian

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Article abstract of DOI:10.1016/S0040-4039(00)96392-5

Isocyanates react with isopropyl or sec-butylmagnesium bromide in the presence of a small amount of Cp2TiCl2 to afford amides with normal alkyl group.A possibl mechanism for this reaction is proposed.

Full text of DOI:10.1016/S0040-4039(00)96392-5

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