2998-08-5

Basic information

• Product Name: SEC-BUTYL ACRYLATE
• Synonyms: SEC-BUTYL ACRYLATE;SEC-BUTYL ACRYLATE RESIN;1-methylpropyl2-propenoate;2-propenoicacid,1-methylpropylester;Acrylic acid, sec-butyl ester;acrylicacid,sec-butylester;s-Butyl acrylate;Butylacrylateresinintoluene
• CAS NO: 2998-08-5
• Molecular Formula: C₇H₁₂O₂
• Molecular Weight: 128.17
• EINECS: 221-072-1
• Mol File: 2998-08-5.mol
• Article Data: 3

Chemical Properties

• Melting Point: -62.3°C
• Boiling Point: 59-60°C 50mm
• Flash Point: 34.5°C
• Appearance: /
• Density: 0.8870
• Vapor Pressure: 6.44mmHg at 25°C
• Refractive Index: 1.4110
• CAS DataBase Reference: SEC-BUTYL ACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: SEC-BUTYL ACRYLATE(2998-08-5)
• EPA Substance Registry System: SEC-BUTYL ACRYLATE(2998-08-5)

Safety Data

• Statements: 10-36/37/38
• Safety Statements: 16-26-36/37/39
• RIDADR: 2348
• HazardClass: 3.1
• PackingGroup: III
• Hazardous Substances Data: 2998-08-5(Hazardous Substances Data)

Usage

General Description

SEC-BUTYL ACRYLATE is a clear, colorless liquid that is commonly used as a monomer in the production of various polymers and resins. It is also used as a raw material in the synthesis of adhesives, coatings, and sealants. This chemical is highly flammable and should be handled with care. It can be harmful if inhaled, ingested, or comes into contact with the skin or eyes. SEC-BUTYL ACRYLATE is considered to be a hazardous substance and should be stored and handled in accordance with strict safety guidelines and regulations.

InChI:InChI=1/C7H12O2/c1-4-6(3)9-7(8)5-2/h5-6H,2,4H2,1,3H3

Upstream product

• 292638-85-8 acrylic acid methyl ester 
• 78-92-2 iso-butanol 
• 79-10-7 acrylic acid 
• 814-68-6 acryloyl chloride 
• 57-57-8 β-Propiolactone 
• 78-76-2 s-butyl bromide 
• 74-86-2 acetylene 

Downstream Products

• 79-10-7 acrylic acid 
• 112032-51-6 3-sec-butoxy-propionic acid sec-butyl ester 
• 132876-34-7 1-(2-sec-Butoxycarbonyl-ethyl)-4-(phenyl-propionyl-amino)-piperidine-4-carboxylic acid methyl ester 
• 1121-05-7 2,3-dimethylcyclopent-2-enone 

Relevant articles and documents

Diastereomeric excess upon cleavage and reformation of diastereomeric alkoxyamines

The thermal reactions of several TEMPO and DEPN (N-(2-methylpropan-2-y1)-N-(1-diethylphosphono-2,2-dimethylpropyl)-aminoxyl) based alkoxyamines were studied by means of 1H and 31P NMR spectroscopy aiming to distinguish the contributions of diastereoselective homolysis and coupling to the total equilibrium diastereomeric distribution. The TEMPO-based compounds reveal no diastereomeric excess while DEPN based compounds show a moderate excess both upon homolysis and coupling. The diastereomeric preference of homolysis for DEPN-(propionate-like) adducts does not depend on the ester group and it is mainly affected by the size of β-substituents. The diastereoselective coupling is sensitive to the total recombination rate constant kc and diastereoselectivity increases with the decrease of kc. Small diastereoselective coupling is found in the recombination of DEPN with sec-butyl isobutyrate radical, where no prochiral centers are formed upon cleavage of corresponding alkoxyamine.

A Contribution to the Nickelcatalyzed Transesterification and to the Addition of Acrylic Acid Methylester to Alcohols

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