3007-74-7

Basic information

• Product Name: N-N-DODECYLANILINE
• Synonyms: Benzenamine, N-dodecyl-;n-dodecyl-benzenamin;n-Dodecyl-N-phenylamine;N-N-DODECYLAMINE;N-N-DODECYLANILINE;n-n-dodecylaniline93+%;N-Phenyl-1-dodecanamine;lauryl(phenyl)amine
• CAS NO: 3007-74-7
• Molecular Formula: C₁₈H₃₁N
• Molecular Weight: 261.45
• EINECS: 221-118-0
• Mol File: 3007-74-7.mol
• Article Data: 33

Chemical Properties

• Melting Point: 25°C
• Boiling Point: 373.2°Cat760mmHg
• Flash Point: 25 °C
• Appearance: /
• Density: 0.9g/cm³
• Vapor Pressure: 9.14E-06mmHg at 25°C
• Refractive Index: 1.509
• Solubility: soluble in Benzene
• PKA: 5.05±0.50(Predicted)
• CAS DataBase Reference: N-N-DODECYLANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-N-DODECYLANILINE(3007-74-7)
• EPA Substance Registry System: N-N-DODECYLANILINE(3007-74-7)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 3007-74-7(Hazardous Substances Data)

Usage

General Description

N-N-Dodecylaniline, with a chemical formula of C18H29N, is a long-chain secondary amine that belongs to the class of organic compounds known as anilines. It is a colorless to pale yellow liquid, insoluble in water, but soluble in most organic solvents. In its pure form, it can produce harmful vapors and is toxic if inhaled, ingested, or absorbed through the skin. Its primary use is as an intermediate in the production of other chemicals such as pharmaceuticals, resins and polymers, particularly in the production of light stabilizers that prevent color loss and the degradation of physical properties in a variety of materials. Its handling requires professional expertise with appropriate safety precautions due to its hazardous properties.

InChI:InChI=1/C18H31N/c1-2-3-4-5-6-7-8-9-10-14-17-19-18-15-12-11-13-16-18/h11-13,15-16,19H,2-10,14,17H2,1H3

Upstream product

• 143-15-7 1-dodecylbromide 
• 62-53-3 aniline 
• 14402-22-3 N-lauryl-α-methylpyridinium iodide 
• 123-91-1 1,4-dioxane 
• 3430-95-3 N-phenyldodecanamide 
• 98-95-3 nitrobenzene 
• 2437-25-4 undecyl cyanide 
• 108-86-1 bromobenzene 
• 124-22-1 n-Dodecylamine 
• 591-50-4 iodobenzene 
• 4292-19-7 1-Iodododecane 
• 108-90-7 chlorobenzene 
• 112-53-8 1-dodecyl alcohol 
• 143-07-7 lauric acid 

Downstream Products

• 115486-65-2 N-dodecyl-toluene-4-sulfonanilide 
• 104-42-7 4-dodecylaniline 
• 854306-07-3 4,N-didodecyl-aniline 
• 62-53-3 aniline 
• 1311478-35-9 C₄₄H₇₄N₄O₂ 
• 5440-15-3 4-chloro-N-dodecylbenzenamine 
• 3663-30-7 N-acetyl-4-n-dodecylaniline 
• 81528-07-6 10-Dodecyl-3-phenyl-10H-pyrimido[4,5-b]quinoline-2,4-dione 
• 200134-00-5 N-ethyl-N-n-dodecylaniline 

Relevant articles and documents

Switchable Imine and Amine Synthesis Catalyzed by a Well-Defined Cobalt Complex

Switchable imine and amine synthesis catalyzed by a tripodal ligand-supported well-defined cobalt complex is presented herein. A large variety of primary alcohols and amines were selectively converted to imines or amines in good to excellent yields. It is discovered that the base plays a crucial role on the selectivity. A catalytic amount of base leads to the imine formation, while an excess loading of base results in the amine product. This strategy on product selectivity also strongly depends on the organometallic catalysts in use. We expect that the present study could provide useful insights toward selective organic synthesis and catalyst design.

Bidentate geometry-constrained iminopyridyl nickel-catalyzed synthesis of amines or imines via borrowing hydrogen or dehydrogenative condensation

The efficient Ni-catalyzed N-alkylation of various anilines with alcohols via borrowing hydrogen is reported using a bidentate geometry-constrained iminopyridyl nickel complex as the catalyst. Substituted benzylic alcohols and short/long chain aliphatic alcohols could be applied as the alkylation sources to couple with aromatic and heteroaromatic amines to give a diverse set of N-alkylation outcomes in moderate to excellent yields. The nickel catalytic system was also suitable for aliphatic amines, selectively delivering the corresponding imines via an acceptorless dehydrogenative condensation strategy.

Alcohol Amination Catalyzed by Copper Powder as a Self-Supported Catalyst

Catalytic alcohol amination is a sustainable reaction for N-alkyl amine synthesis. Homogeneous and supported copper catalysts have long been studied for this reaction and have given some impressive results. In this study, copper powder is found to behave as an active catalyst for alcohol amination, giving better catalytic performance than metal-oxide-supported nanocopper catalysts. Catalyst characterization suggests that the copper powder can be considered as a self-supported nanocopper catalyst (i.e., nanocopper supported on copper particles). These results might promote the study of unsupported transition metal powders in sustainable catalytic reactions.