30222-33-4Relevant academic research and scientific papers
Highly efficient iodine-catalyzed hydroarylation of arenes with styrenes
Chu, Cheng-Ming,Huang, Wan-Ju,Liu, Ju-Tsung,Yao, Ching-Fa
, p. 6881 - 6885 (2007)
Iodine mediates the hydroarylation of styrenes with arenes and heteroarenes to afford 1,1-diarylalkanes in good to high yields. Details regarding the substrate scope and selectivity of this hydroarylation reaction are discussed.
Nickel-Catalyzed Asymmetric Reductive Diarylation of Vinylarenes
Anthony, David,Lin, Qiao,Baudet, Judith,Diao, Tianning
supporting information, p. 3198 - 3202 (2019/02/19)
A nickel-catalyzed asymmetric diarylation reaction of vinylarenes enables the preparation of chiral α,α,β-triarylated ethane scaffolds, which exist in a number of biologically active molecules. The use of reducing conditions with aryl bromides as coupling partners obviates the need for stoichiometric organometallic reagents and tolerates a broad range of functional groups. The application of an N-oxyl radical as a ligand to a nickel catalyst represents a novel approach to facilitate nickel-catalyzed cross-coupling reactions.
