612-15-7

Basic information

• Product Name: 2-METHOXYSTYRENE
• Synonyms: 2-Methoxystyrene, (Stabilized with 4-t-Butylcatechol);1-Vinyl-2-methoxybenzene;o-Methoxystyrene;1-ethenyl-2-methoxybenzene;1-ethenyl-2-methoxy-benzene;2-Vinylanisole, 1-Ethenyl-2-methoxybenzene;2-Vinylanisole 98%;1-ethenyl-2-methoxy-benzen
• CAS NO: 612-15-7
• Molecular Formula: C₉H₁₀O
• Molecular Weight: 134.18
• EINECS: 210-294-4
• Product Categories: Acyclic;Alkenes;Organic Building Blocks
• Mol File: 612-15-7.mol
• Article Data: 71

Chemical Properties

• Melting Point: 29°C
• Boiling Point: 36-43 °C0.5 mm Hg(lit.)
• Flash Point: 135 °F
• Appearance: white or yellow dust
• Density: 0.999 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.514mmHg at 25°C
• Refractive Index: n20/D 1.5540(lit.)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 2-METHOXYSTYRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHOXYSTYRENE(612-15-7)
• EPA Substance Registry System: 2-METHOXYSTYRENE(612-15-7)

Safety Data

• Statements: 10-36/37/38
• Safety Statements: 16-26-36/37/39
• RIDADR: UN 1993 3/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 612-15-7(Hazardous Substances Data)

Usage

Occurrence

Reported found in Origanum vulgare.

InChI:InChI=1/C9H10O/c1-3-8-6-4-5-7-9(8)10-2/h3-7H,1H2,2H3

Upstream product

• 141-52-6 sodium ethanolate 
• 27946-65-2 (2-methoxy-phenethyl)-trimethyl-ammonium; iodide 
• 695-84-1 2-allylphenol 
• 74-88-4 methyl iodide 
• 17333-73-2 phenylium 
• 75-56-9 methyloxirane 
• 13513-82-1 1-(2-methoxyphenyl)ethanol 
• 859312-83-7 di[1-(2-methoxyphenyl)ethyl]ether 
• 529-28-2 4-iodoanisol 
• 7486-35-3 tri-n-butyl(vinyl)tin 
• 135-02-4 ortho-anisaldehyde 
• 578-57-4 2-bromoanisole 
• 593-60-2 Vinyl bromide 
• 5720-06-9 2-Methoxyphenylboronic acid 

Downstream Products

• 81693-79-0 2-n-hexyl-1-methoxybenzene 
• 14804-32-1 2-ethylanisole 
• 279684-32-1 2-(1'-Trimethylsilylhexyl)anisole 
• 62717-78-6 2-(2-methoxyphenyl)oxirane 
• 82807-38-3 1-(2-methoxyphenyl)ethane-1,2-diol 

Relevant articles and documents

Functionalized styrene synthesis via palladium-catalyzed C[sbnd]C cleavage of aryl ketones

We report herein the synthesis of functionalized styrenes via palladium-catalyzed Suzuki–Miyaura cross-coupling reaction between aryl ketone derivatives and potassium vinyltrifluoroborate. The employment of pyridine-oxazoline ligand was the key to the cleavage of unstrained C[sbnd]C bond. A variety of functional groups and biologically important moleculars were well tolerated. The orthogonal Suzuki–Miyaura coupling demonstrated the synthetic practicability.

Application of tungsten oxide supported monatomic catalyst in preparation of aromatic compound by hydrogenolysis of lignin

The invention provides application of a tungsten oxide supported monatomic catalyst in preparation of aromatic compounds by hydrogenolysis of lignin. According to the method, various beta-O-4 model molecules, organic lignin, lignosulfonate and alkali lignin are taken as raw materials, and high-selectivity cracking of aryl ether bonds is realized in a hydrogen atmosphere at the temperature of 150-240 DEG C and the pressure of 0.7-3.0 MPa to obtain the aromatic compound. Compared with the prior art, the method has the advantages that when renewable natural biomass is used as the raw material and different lignin is used as the raw material for conversion, the highest yield of the aromatic bio-oil is 72%. Raw materials are cheap and wide in source; inorganic acid and alkali are not needed, and generation of a large amount of alkali liquor in traditional lignin catalysis is avoided; the method has the characteristics of cheap tungsten-based catalyst, green reaction process, atom economy and the like, and also has the characteristics of mild reaction conditions, high activity and selectivity, environment-friendly reaction process and the like.

Iron-Catalyzed Direct Julia-Type Olefination of Alcohols

Herein, we report an iron-catalyzed, convenient, and expedient strategy for the synthesis of styrene and naphthalene derivatives with the liberation of dihydrogen. The use of a catalyst derived from an earth-abundant metal provides a sustainable strategy to olefins. This method exhibits wide substrate scope (primary and secondary alcohols) functional group tolerance (amino, nitro, halo, alkoxy, thiomethoxy, and S- A nd N-heterocyclic compounds) that can be scaled up. The unprecedented synthesis of 1-methyl naphthalenes proceeds via tandem methenylation/double dehydrogenation. Mechanistic study shows that the cleavage of the C-H bond of alcohol is the rate-determining step.