3023-57-2

Basic information

• Product Name: 2,5-dimethyl-3-phenyl-2,5-hexanediol
• Synonyms: 2,5-dimethyl-3-phenyl-2,5-hexanediol
• CAS NO: 3023-57-2
• Molecular Weight: 222.327
• Mol File: 3023-57-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-dimethyl-3-phenyl-2,5-hexanediol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-dimethyl-3-phenyl-2,5-hexanediol(3023-57-2)
• EPA Substance Registry System: 2,5-dimethyl-3-phenyl-2,5-hexanediol(3023-57-2)

Safety Data

• Hazardous Substances Data: 3023-57-2(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 15463-92-0 dimethyl 2-phenylsuccinate 
• 100-42-5 styrene 
• 67-64-1 acetone 

Relevant articles and documents

DTBB-Catalysed dilithiation of styrene and its methyl-derivatives: Introduction of two electrophilic reagents

The reaction of styrene and some methyl-substituted styrenes 1 with lithium and a catalytic amount of 4,4′-di-tert-butylbiphenyl (DTBB) in the presence of several electrophiles [Me3SiCl, Me2CO, Et2CO, (CH2)5CO, Pr2CO], in THF, at temperatures ranging from -78 to 0°C, gave, after hydrolysis, products 2 resulting from addition of lithium to the olefinic double bond and successive trapping with the electrophilic reagent. When a carbonyl compound was used as electrophile, mixtures of the monoaddition-reduction compounds 3 and 4 were obtained as by-products, which could be easily separated from the diaddition products 2.