3023-92-5 Usage
Uses
Used in Organic Synthesis:
TRICYCLOHEXYLTIN BROMIDE is used as a reagent for the functionalization of various organic compounds, enabling the formation of carbon-carbon and carbon-heteroatom bonds.
Used in Stille Coupling:
TRICYCLOHEXYLTIN BROMIDE is used as a reagent in Stille coupling reactions, a type of cross-coupling reaction that facilitates the formation of carbon-carbon bonds between an organotin compound and an organic halide.
Used in Sonogashira Coupling:
TRICYCLOHEXYLTIN BROMIDE is used as a reagent in Sonogashira coupling reactions, a palladium-catalyzed cross-coupling reaction that allows for the formation of carbon-carbon bonds between an organotin compound and an alkyne.
Used in Nucleophilic Substitution:
TRICYCLOHEXYLTIN BROMIDE is used as a reagent in nucleophilic substitution reactions, where the tricyclohexyltin group is transferred to an organic molecule, leading to the formation of new chemical bonds.
Used in Catalysis:
TRICYCLOHEXYLTIN BROMIDE is used as a catalyst in various chemical transformations, enhancing the efficiency and selectivity of the reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 3023-92-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,0,2 and 3 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 3023-92:
(6*3)+(5*0)+(4*2)+(3*3)+(2*9)+(1*2)=55
55 % 10 = 5
So 3023-92-5 is a valid CAS Registry Number.
InChI:InChI=1/3C6H11.BrH.Sn/c3*1-2-4-6-5-3-1;;/h3*1H,2-6H2;1H;/q;;;;+1/p-1/rC18H33BrSn/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2
3023-92-5Relevant academic research and scientific papers
Further study of tris(cyclohexyl)stannane compounds, Cy3SnX. Syntheses of the compounds with X = Br, I, N3 and NCS and redetermination of the crystal structures of Cy3SnX (X = Br and I)
Howie, R. Alan,Moura, Marcelo V.H.,Wardell, James L.,Wardell, Solange M.S.V.
, p. 2331 - 2336 (2008/10/09)
Compound sythesis and far IR data are presented for various Cy 3SnX compounds. Redeterminations of the crystal structures of tris(cyclohexyl)tin bromide and iodide, Cy3SnBr and Cy 3SnI, confirm their molecular nature providing, in particular, a revised estimate of the Sn-I bond length, now 2.7463(6) ?. The nature of the solid state structure of Cy3SnCl is also discussed.
Electrophilic cleavage of tin-alicyclic and tin-aryl bonds involving the synthesis of cyclohexyl-tin, -tellurium and -antimony compounds - Part I
Singhal, Kiran
, p. 542 - 544 (2007/10/02)
Cyclohexyl-tin, -tellurium and -antimony halides have been obtained in good yields by the electrophilic cleavage of Sn-C bond(s) from symmetrical and unsymmetrical cyclohexyl tins, CynPnPh4-n (n = 1, 2, 4) employing Br2, I2, ICl, IBr, TeCl4 and SbCl5 in CCl4 under mild conditions.