302321-78-4

Basic information

• Product Name: 2,4-Cyclohexadien-1-one, 4-(5,5-dimethyl-1,3-dioxan-2-yl)-6,6-dimethoxy-
• CAS NO: 302321-78-4
• Molecular Formula: C14H20O5
• Molecular Weight: 268.31
• Mol File: 302321-78-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2,4-Cyclohexadien-1-one, 4-(5,5-dimethyl-1,3-dioxan-2-yl)-6,6-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Cyclohexadien-1-one, 4-(5,5-dimethyl-1,3-dioxan-2-yl)-6,6-dimethoxy-(302321-78-4)
• EPA Substance Registry System: 2,4-Cyclohexadien-1-one, 4-(5,5-dimethyl-1,3-dioxan-2-yl)-6,6-dimethoxy-(302321-78-4)

Safety Data

• Hazardous Substances Data: 302321-78-4(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 182345-46-6 5,5-Dimethyl-2-(4-hydroxy-3-methoxyphenyl)-1,3-dioxane 

Downstream Products

• 19463-48-0 5-chlorovanillin 
• 18268-76-3 6-chlorovaniline 
• 25181-40-2 (1R,2S,3S)-cyclopropane-1,2,3-triyltris((4-bromophenyl)methanone) 
• 1404575-78-5 C₂₃H₂₇NO₅ 

Relevant articles and documents

The hetero Diels-Alder reactions of masked o-benzoquinones with nitroso compounds

The first examples of hetero Diels-Alder reaction of masked o-benzoquinones with nitroso dienophiles leading to novel and highly functionalized heterocycles, which are potential intermediates for nitrogenous natural products are reported.

Unanticipated participation of HCl in nucleophilic chlorination reaction: Expedient route to meta chlorophenols

o-Quinone monoketals participated in a 1,4-addition reaction with HCl furnishing m-chlorophenols in high yields. Several readily available o-quinone monoketals were selected to display the generality of this serendipitous and unprecedented reaction and the results are presented herein.

Photoinduced Decarbonylative Rearrangement of Bicyclo[2.2.2]Octenones: Synthesis of the Marasmane Skeleton

The marasmane sesquiterpenoid structure can be found in the skeleton of a variety of natural products bearing interesting bioactivity. The unique fused-5,6,3-tricyclic ring structure, in which the rings are cis-fused and the five- and three-membered rings are mutually trans, provides a synthetic challenge for organic chemists. In this work, we took advantage of the photoinduced decarbonylative rearrangement of bicyclo[2.2.2]octenone to develop a new methodology for construction of the highly functionalized fused-5,6,3-tricyclic ring structure in a concise reaction sequence.