30262-96-5

Basic information

• Product Name: 2-Butanone, 4-phenyl-4-(trimethylsilyl)-
• CAS NO: 30262-96-5
• Molecular Formula: C13H20OSi
• Molecular Weight: 220.387
• Mol File: 30262-96-5.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 4-phenyl-4-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 4-phenyl-4-(trimethylsilyl)-(30262-96-5)
• EPA Substance Registry System: 2-Butanone, 4-phenyl-4-(trimethylsilyl)-(30262-96-5)

Safety Data

• Hazardous Substances Data: 30262-96-5(Hazardous Substances Data)

Upstream product

• 1817-57-8 4-phenyl-3-butyne-2-one 
• 917-54-4 methyllithium 
• 107486-95-3 (E)-3-phenyl-1-trimethylsilyl-2-propen-1-one 
• 4360-47-8 cinnamonitrile 
• 56919-90-5 (E)-4-(trimethylsilyl)but-3-en-2-ol 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 5930-98-3 4-trimethylsilyl-3-butyn-2-one 
• 1896-62-4 (E)-benzalacetone 
• 75-77-4 chloro-trimethyl-silane 
• 937-53-1 (Z)-4-phenylbut-3-en-2-one 
• 49750-09-6 (E)-1-trimethylsilyl-1-buten-3-one 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 18026-87-4 1,1,1-trichloro-2,2,2-trimethyldisilane 

Downstream Products

• 15325-61-8 3-methyl-1-phenyl-1-butene 
• 15325-61-8 (E)-(3-methylbut-1-en-1-yl)benzene 
• 79239-10-4 2-methyl-4-phenyl-4-trimethylsilylbutan-2-ol 
• 30263-02-6 1-Phenyl-1-trimethylsilyl-3-butanol 

Relevant articles and documents

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Palladium/Me3SiOTf-catalyzed bis-silylation of α,β-unsaturated carbonyl compounds without involving oxidative addition of disilane

In the presence of a catalytic amount of Me3SiOTf and palladium(0), the addition of disilane to α,β-unsaturated carbonyl compounds proceeds under very mild conditions via η3-siloxyallylpalladium generated by the reaction of enone, en

Synthesis of β-silylated olefins from α,β-unsaturated aldehydes and ketones

α,β-Unsaturated aldehydes and ketones such as phorone, benzalacetone, benzalacetophenone, 4-(2-furyl)-3-buten-4-one and β-ionone, react with TMS-Cl in the presence of Li in THF to give conjugated β-silylated enoxysilanes. Hydrolysis of this compounds in a