30277-63-5

Basic information

• Product Name: Benzene, 1-methoxy-4-(1-methoxy-2-propenyl)-
• CAS NO: 30277-63-5
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Mol File: 30277-63-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-(1-methoxy-2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-(1-methoxy-2-propenyl)-(30277-63-5)
• EPA Substance Registry System: Benzene, 1-methoxy-4-(1-methoxy-2-propenyl)-(30277-63-5)

Safety Data

• Hazardous Substances Data: 30277-63-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 140-67-0 Estragole 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 1826-67-1 vinyl magnesium bromide 
• 81701-30-6 (E)-4-methoxycinnamyl acetate 
• 94607-41-7 (E)-1-(4-methoxyphenyl)-3-chloropropene 
• 24393-56-4 ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate 
• 943-89-5 (E)-3-(4-methoxyphenyl)acrylic acid 
• 53484-50-7 (E)-p-methoxy-cinnamyl alcohol 
• 53580-61-3 4-(1-hydroxy-2-propenyl)phenol 
• 74-88-4 methyl iodide 

Downstream Products

• 1315331-66-8 C₁₈H₂₇NO₅S 
• 1315331-65-7 C₁₈H₂₇NO₅S 
• 1315331-67-9 C₁₆H₂₃NO₄S 
• 1315331-68-0 C₁₆H₂₃NO₄S 
• 1315331-70-4 C₁₂H₁₅NO₃ 
• 1315331-69-1 C₁₂H₁₅NO₃ 
• 35856-81-6 1-methoxy-4-[(1E)-3-phenylprop-1-en-1-yl]benzene 

Relevant articles and documents

Nickel-Catalyzed Arylation of C(sp3)-O Bonds in Allylic Alkyl Ethers with Organoboron Compounds

A nickel-catalyzed cross-coupling of allylic alkyl ethers with organoboron compounds through the cleavage of the inert C(sp3)-O(alkyl) bonds is described. Several types of allylic alkyl ethers can be coupled with various boronic acids or their derivatives to give the corresponding products in good to excellent yields with wide functional group tolerance and excellent regioselectivity. The gram-scale reaction and late-stage modification of biologically active compounds further prove the practicality of this synthetic method.

The photochemistry of ring-substituted cinnamyl acetates

The photochemistry of the (E)-cinnamyl acetates ((E)-1-aryl-3-propenyl acetates, 8a-8e) with substituents H, 4-CH3O, 3-CH3O, 4-CF3, and 3-CF3, respectively, was examined in both cyclohexane and methanol solvents. Alkene isomerization (E to Z) occurred more efficiently than other reactions and evidence is presented that this process occurs from the excited triplet state. In a slower process, 1,3-migration of the acetoxy group led to the rearranged 3-aryl-3-propenyl acetate isomers (9a-9e) as the major pathway, particularly in cylohexane. In methanol, the isomeric ethers 3-aryl-3-methoxypropene (14) and 1-aryl-3-methoxypropene (15) were formed by reaction of methanol with the photochemically generated cation. The combined yield of 14 and 15 (95% and 5%, respectively) was quantitative for the 4-methoxyphenyl compound (8b). Independent irradiations of the isomers 9a-9c demonstrated that the ethers 14 and 15 were primary photoproducts from 8 and not secondary photoproducts from 9. Fluorescence quantum yields and excited singlet state lifetimes indicated that the reactions, other than the E to Z isomerization, are from the excited singlet state.

Electrochemical Methoxylation of Allyl and Propenyl Derivatives of Phenol and Phenol Ethers

Anodic oxidation of a methanolic solution of a number of phenols and phenol ethers (anethole, estragole, safrole, isosafrole, eugenol, and isoeugenol) in a single cell at constant current, with use of sodium methoxide or sodium methoxide-sodium perchlorate as the supporting electrolyte, afforded substitution and addition products, some of them not described previously in the literature.