303142-40-7Relevant articles and documents
Gold-catalyzed intramolecular [3 + 2]-cycloaddition of arenyne-yne functionalities
Lian, Jian-Jou,Chen, Po-Chiang,Lin, Yau-Ping,Ting, Hao-Chun,Liu, Rai-Shung
, p. 11372 - 11373 (2007/10/03)
We report a new efficient intramolecular [3 + 2]-cycloaddition of unactivated arenyne (or enyne)-yne functionalities, catalyzed mainly by the AuPPh3SbF6 complex (2 mol %) under ambient conditions. The value of this cyclization is ref
Novel chemistry of α-tosyloxy ketones: Applications to the solution- and solid-phase synthesis of privileged heterocycle and enediyne libraries
Nicolaou,Montagnon,Ulven,Baran,Zhong,Sarabiat
, p. 5718 - 5728 (2007/10/03)
New synthetic technologies for the preparation and elaboration of α-tosyloxy ketones in solution and on solid-phase are described. Both olefins and ketones serve as precursors to these relatively stable chemical entities: olefins via a novel one-pot epoxi