30713-67-8Relevant academic research and scientific papers
Electrochemical Oxidative Aromatizationof 9-Substituted 9,10-Dihydroacridines: Cleavage of C–H vs C–X Bond
Chupakhin, Oleg N.,Shchepochkin, Alexander V.,Charushin, Valery N.,Maiorova, Anna V.,Kulikova, Tatyana V.,Shunyaev, Konstantin Yu.,Enyashin, Andrey N.,Slepukhin, Pavel A.,Suvorova, Anna I.
, p. 956 - 963 (2019)
[Figure not available: see fulltext.] Reactivity of dihydroacridines bearing a С–X fragment at the geminal C-9 atom (where X = C, N, O, P, S) on anode has been investigated by means of electrochemical oxidation and thermodynamic and quantum-chemical calculations. The electrochemical oxidation results either in the formation of the 9-substituted acridines or in the cleavage of the C–X bond. This dual behavior of dihydroazines is analogous to processes reported in literature that take place upon treatment with chemical oxidants.
