3095-87-2Relevant articles and documents
Supramolecular architecture of [AsPh2Br2]2[(Br3)?…(Br2)…(Br3)?] obtained by bromination of (AsPh2)2S
Silaghi-Dumitrescu, Luminita,Attia, Amr A.A.,Silaghi-Dumitrescu, Radu,Blake, Alexander J.,Sowerby, D. Bryan
, p. 120 - 126 (2017/09/14)
Bromination of (AsPh2)2S leads to cleavage of the sulfide bridge to give AsPh2Br when 1 mol of bromine is used but with 2 mols the product is the polybromide, [AsPh2Br2]2[Br8], c
Synthesis and characterization of Se-organoarsanyl selenocarboxylates
Kanda,Mizoguchi,Koike,Murai,Kato
, p. 282 - 286 (2007/10/02)
Sodium selenocarboxylates were found to react with organoarsanyl chlorides Ph3-(n)AsCl(n) 1-3 (n = 1, 2, 3) to give the corresponding Se-organoarsanyl esters RCOSeAsPh2 (5), (RCOSe)2AsPh (6) and (RCOSe)3As (7) in good yields. The reaction of Se-diphenylarsanyl 4-methylbenzenecarboselenoate 5g with phenylselenenyl bromide and phenyltellurenyl iodide afforded the corresponding Se-phenyl-selenenyl 13 and Se-phenyltellurenyl esters 14 in moderate yields, while the reaction with sodium phenoxide gave sodium 4- methylbenzenecarboselenoate (4g), phenyl 4-methylbenzoate (11) and phenoxydiphenylarsine (12), indicating the attack of phenoxy anion to both the carbonyl carbon and arsenic atoms.