30956-41-3

Basic information

• Product Name: Ethyl 6-oxoheptanoate
• Synonyms: 6-Ketoenanthic acid ethyl ester;6-Oxoheptanoic acid ethyl ester;Ethyl 6-oxoheptanoate
• CAS NO: 30956-41-3
• Molecular Formula: C₉H₁₆O₃
• Molecular Weight: 172.22
• Mol File: 30956-41-3.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 107-108 °C(Press: 9 Torr)
• Appearance: /
• Density: 0.9795 g/cm3(Temp: 25 °C)
• CAS DataBase Reference: Ethyl 6-oxoheptanoate(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl 6-oxoheptanoate(30956-41-3)
• EPA Substance Registry System: Ethyl 6-oxoheptanoate(30956-41-3)

Safety Data

• Hazardous Substances Data: 30956-41-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 2854, 1951 DOI: 10.1021/ja01150a126

Upstream product

• 1071-71-2 ethyl 6-chloro-6-oxohexanoate 
• 506-82-1 dimethylcadmium 
• 18815-73-1 methylzinc iodide 
• 917-65-7 methylaluminum dichloride 
• 3128-07-2 6-oxoheptanoic acid 
• 64-17-5 ethanol 
• 13837-45-1 1-ethoxy-1-cyclopropanol 
• 78-94-4 methyl vinyl ketone 
• 55099-47-3 (+/-)-Ethyl 6-hydroxyheptanoate 
• 1670-46-8 2-acetylcyclopentanaone 
• 78-93-3 butanone 
• 140-88-5 ethyl acrylate 
• 583-60-8 2-Methylcyclohexanone 
• 822-87-7 2-Chlorocyclohexanone 

Downstream Products

• 1670-46-8 2-acetylcyclopentanaone 
• 55099-47-3 (+/-)-Ethyl 6-hydroxyheptanoate 
• 36651-17-9 ethyl 5-(2-methyl-1,3-dioxolan-2-yl)pentanoate 
• 110061-31-9 2-(2,4-dinitro-phenyl)-6-methoxy-3-methyl-2,4,5,6-tetrahydro-cyclopentapyrazole 
• 15419-62-2 1-(2,4-dinitrophenyl)-3-methyl-1,4,5,6-tetrahydrocyclopenta[c]pyrazole 
• 36651-23-7 5-(2-methyl-[1,3]dioxolan-2-yl)-pentan-1-ol 
• 678986-19-1 5-(3-phenyl-5,6,7,8-tetrahydro-[1,8]naphthyridin-2-yl)-pentanoic acid ethyl ester 
• 583-60-8 2-Methylcyclohexanone 
• 1314796-69-4 C₂₁H₁₆F₄N₄O₂ 
• 1314796-68-3 C₂₁H₁₆F₄N₄O 
• 1314796-67-2 2-{4-[5-(4-chloro-3-trifluoromethylphenyl)-[1,3,4]oxadiazol-2-yl]-butyl}-[1,8]naphthyridine 
• 1314796-66-1 2-{4-[5-(3-chloro-4-trifluoromethoxyphenyl)-[1,3,4]oxadiazol-2-yl]butyl}-[1,8]naphthyridine 
• 1314796-64-9 C₂₂H₁₆F₆N₄O 

Relevant articles and documents

Iron-Catalyzed C(sp 3)-H Alkylation through Ligand-to-Metal Charge Transfer

We report the FeCl 3-catalyzed alkylation of nonactivated C(sp 3)-H bonds. Photoinduced ligand-to-metal charge transfer at the iron center generates chlorine radicals that then preferentially abstract hydrogen atoms from electron-ric

An efficient method for retro-Claisen-type C-C bond cleavage of diketones with tropylium catalyst

The retro-Claisen reaction is frequently used in organic synthesis to access ester derivatives from 1,3-dicarbonyl precursors. The C-C bond cleavage in this reaction is usually promoted by a number of transition-metal Lewis acid catalysts or organic Br?nsted acids/bases. Herein we report a new convenient and efficient method utilizing the tropylium ion as a mild and environmentally friendly organocatalyst to mediate retro-Claisen-type reactions. Using this method, a range of synthetically valuable substances can be accessed via solvolysis of 1,3-dicarbonyl compounds.

Copper-catalyzed remote sp3 C-H chlorination of alkyl hydroperoxides

A copper-catalyzed methodology to functionalize remote sp3 C-H bonds in alkyl hydroperoxides is presented. The atom-transfer chlorination utilizes simple ammonium chloride salts as the chlorine source, and the internal redox process requires no external redox reagents.