31144-23-7Relevant academic research and scientific papers
Facile synthesis of phosphaamidines and phosphaamidinates using nitrilium ions as an imine synthon
Van Dijk, Tom,Burck, Sebastian,Rong, Mark K.,Rosenthal, Amos J.,Nieger, Martin,Slootweg, J. Chris,Lammertsma, Koop
supporting information, p. 9068 - 9071 (2014/10/15)
Readily accessible nitrilium triflates are convenient imine building blocks for the expedient synthesis of a novel class of 1,3-P,N ligands as demonstrated for the reaction with primary phosphanes. This procedure allows variation of all substituents. X-ray crystal structures are reported for nitrilium ions, phosphaamidines, and three phosphaamidinate complexes. The lithium phosphaamidinate is N coordinated and its reaction with [AuCl(tht)] (tht=tetrahydrothiophene) gives a unique P-bridged gold trimer, while a P,N-bidentate complex results from [{RhCl(cod)}2]. The nitrilium ion methodology allows extension of the 1,3-P,N motive to bis(imino)phosphanes, which are the neutral phosphorus analogues of the valuable β-diketiminate ligand.
Transition metal-free one-pot synthesis of 2-substituted 3-carboxy-4-quinolone and chromone derivatives
Lin, Jian-Ping,Long, Ya-Qiu
supporting information, p. 5313 - 5315 (2013/06/27)
A novel one-pot synthesis of the 2-substituted 3-carboxy-4-quinolone/ chromone derivatives from readily available 3-oxo-3-arylpropanoates and amides/acyl chlorides is reported, without any transition metal aid. The Royal Society of Chemistry 2013.
Parallel copper catalysis: Diastereoselective synthesis of polyfunctionalized azetidin-2-imines
Xing, Yanpeng,Zhao, Hongyang,Shang, Qiongyi,Wang, Jing,Lu, Ping,Wang, Yanguang
supporting information, p. 2668 - 2671 (2013/07/19)
An efficient and diastereoselective synthesis of highly functionalized azetidin-2-imines has been achieved through a parallel catalysis strategy, including a copper-catalyzed azide-alkyne cycloaddition, a copper-catalyzed Csp-Csp2 cr
One-pot synthesis of 2-imidazolines via the ring expansion of imidoyl chlorides with aziridines
Kuszpit, Michael R.,Wulff, William D.,Tepe, Jetze J.
experimental part, p. 2913 - 2919 (2011/06/19)
We herein report a simple and convenient one-pot synthesis of highly substituted 2-imidazolines in a regiocontrolled and stereospecific matter through the ring expansion reaction of an imidoyl chloride with an aziridine, analogous to the Heine reaction.
Synthesis of chlorinated bicyclic C-fused tetrahydrofuro[3,2- c ]azetidin-2-ones
Ram, Ram N.,Kumar, Neeraj,Singh, Nem
supporting information; experimental part, p. 7408 - 7411 (2011/02/22)
Some bicyclic C-fused chlorinated tetrahydrofuro[3,2-c]azetidin-2-ones were prepared by a fairly general route involving Staudinger reaction of allylic/propargylic imidates with dichloroketene followed by highly diastereoselective CuCl/PMDETA-catalyzed 5-
