31189-02-3Relevant academic research and scientific papers
Oxidative Alkoxylation/Dehydrogenation of Unactivated Cyclic Ketones with Simple Alcohols: Direct Route to α-Alkoxy Cycloenones
Yan, Yizhe,Li, Shaoqing,Wang, Jianyong
, p. 6474 - 6477 (2020/10/02)
An oxidative functionalization of cyclopentanones or cyclohexanones with simple alcohols was first demonstrated, affording a series of 2-alkoxycyclopent-2-en-1-ones or 2-alkoxycyclohex-2-en-1-ones in moderate to excellent yields. The reaction was involved in tandem iodization, substitution, oxidation and addition-elimination processes in one pot. This method is highly atom-economical and operationally simple.
Rhodium-catalyzed ring opening of vinyl epoxides with alcohols and aromatic amines
Fagnou, Keith,Lautens, Mark
, p. 2319 - 2320 (2007/10/03)
(equation presented) [Rh(CO)2Cl]2 is an effective catalyst for the ring opening of vinyl epoxides with alcohols and aromatic amines under neutral conditions at room temperature. The reaction occurs with excellent diastereo- and regioselectivity (>20:1) giving the trans-1,2-amino alcohols or alkoxy alcohols for a wide range of substrates. The regio- and stereochemistry of these reactions is complementary to that typically obtained with palladium-catalyzed ring openings of vinyl epoxides.
SYNTHESIS OF DIOSPHENOL ETHERS BY MEANS OF ALKOXYTRIMETHYLSILANES
Ponaras, A. A.,Meah, Md. Younus
, p. 4953 - 4956 (2007/10/02)
α-Diketones may be O-alkylated with a variety of alkoxytrimethylsilanes.
