31189-02-3

Basic information

• Product Name: 2-Cyclohexen-1-one,2-(1-methylethoxy)-(9CI)
• Synonyms: 2-Cyclohexen-1-one,2-(1-methylethoxy)-(9CI)
• CAS NO: 31189-02-3
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.20626
• Product Categories: CYCLOHEXANONE
• Mol File: 31189-02-3.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Cyclohexen-1-one,2-(1-methylethoxy)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one,2-(1-methylethoxy)-(9CI)(31189-02-3)
• EPA Substance Registry System: 2-Cyclohexen-1-one,2-(1-methylethoxy)-(9CI)(31189-02-3)

Safety Data

• Hazardous Substances Data: 31189-02-3(Hazardous Substances Data)

Upstream product

• 1825-64-5 isopropoxytrimethylsilane 
• 10316-66-2 2-hydroxy-2-cyclohexen-1-one 
• 108-94-1 cyclohexanone 
• 67-63-0 isopropyl alcohol 
• 6705-51-7 3,4-epoxycyclohexene 

Relevant articles and documents

Oxidative Alkoxylation/Dehydrogenation of Unactivated Cyclic Ketones with Simple Alcohols: Direct Route to α-Alkoxy Cycloenones

An oxidative functionalization of cyclopentanones or cyclohexanones with simple alcohols was first demonstrated, affording a series of 2-alkoxycyclopent-2-en-1-ones or 2-alkoxycyclohex-2-en-1-ones in moderate to excellent yields. The reaction was involved in tandem iodization, substitution, oxidation and addition-elimination processes in one pot. This method is highly atom-economical and operationally simple.

SYNTHESIS OF DIOSPHENOL ETHERS BY MEANS OF ALKOXYTRIMETHYLSILANES

α-Diketones may be O-alkylated with a variety of alkoxytrimethylsilanes.