31198-76-2

Basic information

• Product Name: p-mentha-1(6),8-dien-2-one oxime
• Synonyms: p-mentha-1(6),8-dien-2-one oxime;2-Methyl-5-(1-methylethenyl)-2-cyclohexen-1-one oxime;2-Methyl-5-isopropenyl-2-cyclohexene-1-oneoxime;Carvone oxime;p-Mentha-6(1),8-dien-2-one oxime;N-(2-methyl-5-prop-1-en-2-ylcyclohex-2-en-1-ylidene)hydroxylamine
• CAS NO: 31198-76-2
• Molecular Formula: C₁₀H₁₅NO
• Molecular Weight: 165.2322
• EINECS: 250-510-4
• Mol File: 31198-76-2.mol
• Article Data: 2

Chemical Properties

• Melting Point: 92-93 °C
• Boiling Point: 279°Cat760mmHg
• Flash Point: 164.1°C
• Appearance: /
• Density: 1g/cm³
• Vapor Pressure: 0.0005mmHg at 25°C
• Refractive Index: 1.513
• PKA: 11.88±0.60(Predicted)
• CAS DataBase Reference: p-mentha-1(6),8-dien-2-one oxime(CAS DataBase Reference)
• NIST Chemistry Reference: p-mentha-1(6),8-dien-2-one oxime(31198-76-2)
• EPA Substance Registry System: p-mentha-1(6),8-dien-2-one oxime(31198-76-2)

Safety Data

• Hazardous Substances Data: 31198-76-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H15NO/c1-7(2)9-5-4-8(3)10(6-9)11-12/h4,9,12H,1,5-6H2,2-3H3/b11-10-

Upstream product

• 99-49-0 Carvone 
• 60-29-7 diethyl ether 
• 52528-33-3 1-chloro-p-menth-8-en-2-one oxime 
• 64-17-5 ethanol 
• 7732-18-5 water 
• 563-41-7 semicarbazide hydrochloride 
• 138-86-3 limonene. 
• 64133-31-9 1-phenylamino-4-isopropenyl-1-methyl-6-cyclohexanoxime 
• 65877-16-9 (R)-p-mentha-6,8-dien-2-one-(Z)-oxime 
• 2051-55-0 (S)-p-mentha-6,8-dien-2-one-(Z)-oxime 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 

Downstream Products

• 3792-53-8 2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 63843-08-3 8-chloro-p-menth-6-en-2-one oxime 
• 499-70-7 carvomenthone 
• 2051-53-8 5-isopropyl-2-methylphenylamine 
• 53567-64-9 carvylamine 
• 358359-87-2 (2S,4S)-p-mentha-6,8-dien-2-ylamine 
• 74837-96-0 p-menth-6-en-2-one oxime 
• 1128-28-5 4-aminothymol 
• 1628072-73-0 (E)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone O-4-nitrobenzoyl oxime 
• 1628072-71-8 (E)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone O-4-methylbenzoyl oxime 
• 1628072-70-7 (E)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone O-4-aminobenzoyl oxime 
• 1628072-69-4 (E)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone O-butanoyl oxime 
• 34349-56-9 (E)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone O-benzoyl oxime 

Relevant articles and documents

Gold nanoparticles supported on ceria promote the selective oxidation of oximes into the corresponding carbonylic compounds

Gold supported on ceria (Au/CeO2) is a highly active and selective catalyst for the aerobic oxidation of oximes to the corresponding carbonylic compounds. This reaction can be carried out in a mixture of ethanol- water by oxygen with a complete selectivity and very high conversion using Au/CeO2 as a catalyst. This process appears to be general and aliphatic as well as oximes from aromatic ketones can be converted to the carbonylic compound in the absence of corrosive Broensted acids and without producing aqueous wastes. One example of particular industrial relevance is the transformation of carvone oxime into carvone.