313673-19-7

Upstream product

• 67-56-1 methanol 
• 313673-21-1 (2S,5R,1'S)-2-(tert-Butyl)-5-(1'-hydroxy-1'-phenylmethyl)-2,5-diethyl-1,3-dioxolan-4-one 
• 22946-43-6 (E)-methyl-2-methyl-3-phenylacrylate 
• 100-52-7 benzaldehyde 

Relevant academic research and scientific papers

Catalyst-directed guidance of sulfur-substituted enediolates to stereoselective carbon-carbon bond formation with aldehydes

A highly chemo-, regio-, and stereoselective glycolate aldol reaction of sulfur-substituted enediolates with aldehydes was developed by employing a l-cyclohexylglycine-derived chiral iminophosphorane as a catalyst. The key for establishing this protocol i

A Mechanistically Guided Design Leads to the Synthesis of an Efficient and Practical New Reagent for the Highly Enantioselective, Catalytic Dihydroxylation of Olefins

(Equation presented) The catalytic asymmetric dihydroxylation of olefins has been accomplished with high enantioselectivities using a proline-based catalyst. The pre-transition-state assembly for styrene is shown.

Addition reactions of aldehydes to lithium enolates of 1,3-dioxolan-4-ones: A configurational reassessment

The results for the addition reactions of chiral lithium (2S)-enolates of 1,3-dioxolan-4-ones to aldehydes and to acetophenone, yielding the corresponding dioxolanone alcohols have been revised. The results reported herein differ from those reported in th