31525-67-4

Usage

Uses

Used in Chemical Synthesis:
4,4-Dimethoxy-2-methyl-2-butanol 97 is used as a synthetic building block for the creation of various chemical compounds. Its unique molecular structure allows it to be a valuable component in the synthesis process.
Used in Microwave-Mediated Synthesis:
In the field of microwave-mediated synthesis, 4,4-dimethoxy-2-methyl-2-butanol 97 is used as a reactant for the synthesis of 2,2-dimethyl-2H-chromones. These chromones are important intermediates in the production of various pharmaceuticals and other chemical products.
Used in the Preparation of DCP Analogs:
4,4-Dimethoxy-2-methyl-2-butanol 97 is also utilized in the preparation of alkyl substituted 3′R,4′R-di-O-(-)-camphanoyl-2′,2′-dimethyldihydropyrano[2,3-f]chromone (DCP) analogs. DCP analogs have potential applications in various fields, including pharmaceuticals and materials science.

InChI:InChI=1/C7H16O3/c1-7(2,8)5-6(9-3)10-4/h6,8H,5H2,1-4H3

Upstream product

• 5436-21-5 acetylacetaldehyde dimethyl acetal 
• 75-16-1 methylmagnesium bromide 
• 74-88-4 methyl iodide 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 107-86-8 3,3-dimethyl acrylaldehyde 
• 25983-76-0 isoevodionol 
• 30390-18-2 5-Hydroxy-8,8-dimethyl-6-(2-methylbutanoyl)-4-phenyl-2H,8H-benzo<1,2-b:3,4-b'>dipyran-2-one 
• 5302-74-9 mammea A/BB cyclo D 
• 98244-54-3 (+/-)-surangin A 
• 98216-07-0 6,6-Bis-((E)-3,7-dimethyl-octa-2,6-dienyl)-7-hydroxy-8-(2-methyl-butyryl)-4-propyl-6H-chromene-2,5-dione 
• 66003-49-4 mupamine 
• 108937-55-9 11-benzyloxy-1-hydroxy-3,12-dihydro-3,3-dimethylpyrano<2,3-c>acridin-7-one 
• 34187-25-2 candidine 
• 34187-26-3 5-hydroxy-6'',6''-dimethylpyrano<3'',2'':6,7>flavone 
• 54287-99-9 5-hydroxy-2,2-dimethyl-2H-chromene-6-carbaldehyde 
• 22562-09-0 (+/-)-Apetatolide 
• 548-28-7 (+/-)-Inophyllum C 
• 548-27-6 calophyllolide 

Relevant academic research and scientific papers

Asymmetric Solid-Phase Synthesis of (3′R,4′R)-Di-O-cis-acyl 3-Carboxyl Khellactones

Matrix Presented We describe a practical parallel synthesis of (3′R,4′R)-di-O-cis-acyl 3-carboxyl khellactones on a solid phase in high yield. The highlights of this synthesis include a Knoevenagel condensation, asymmetric dihydroxylation, catalyzed acylation, and product cleavage from the solid support.

Total synthesis of isorobustin

The synthesis of isorobustin 1 in four steps from 5-methoxyresorcinol proceeds in an overall yield of 34%. The key step involves the arylation of a 4-hydroxy-2H-l-benzopyran-2-one 6 by 3,4-methylenedioxyphenyllead triacetate 9 in a chemoselective and regioselective manner.

Fructose 1,6-Diphosphate Aldolase Catalyzed Stereoselective Synthesis of C-Alkyl and N-Containing Sugars: Thermodynamically Controlled C-C Bond Formations.

Fructose 1,6-diphosphate aldolase catalyzed aldol condensations have been used in syntheses of several new N-containing and C-alkyl sugars on 4-20 mmol scales.The enzyme is highly specific for dihydroxyacetone phosphate as donor but accepts a number of achiral and chiral aldehydes (both D and L isomers) as acceptors.Due to the reversible nature of the aldol reaction, a thermodynamically controlled approach was employed for the syntheses in which racemic aldehydes were used as substrates and thermodynamically more stable products were preferentially produced.